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COMMUNICATION
Journal Name
7
Heterogeneous catalytic systems bearing Fe-porphyrins for
1
7
8344; (e) N. B. McKeown and P. M. Budd, Chem. Soc. Rev. 2006,
3
Reviews: (a) Y. Zhang and J. Y. Ying, ACS Catal. 2015,
2
DOI: 10.1039/C6CC10005H
the carbene insertion to N-H bonds are rare. Moreover, H-
MFePN (the complete conversion of aniline in 3 min, 1 mol%
Fe-porphyrins, r.t.) was much superior to heterogeneous
systems (the complete conversion of aniline in 20 or 30 min, 1
5
, 675-683.
2
5
, 2681-
691; (b) P. Kaur, J. T. Hupp and S. T. Nguyen, ACS Catal. 2011,
, 819-835; (c) Y. –L. Wong, J. M. Tobin, Z. Xu and F. Vilela, J.
, 18677-18686: (d) L. Pan, M. –Y. Xu, L.
J. Feng, Q. Chen, Y. –J. He and B. –H. Han, Polym. Chem.
016, , 2299-2307; (e) S. Bhunia, B. Banerjee and A. Bhaumik,
1
1
7
Mater. Chem. A 2016,
–
2
Chem. Commun. 2015, 51, 5020-5023; (f) S. Xu, K. Song, T. Li
and B. Tan, J. Mater. Chem. A 2015, , 1272-1278.
(a) J. –X. Jiang, F. Su, A. Trewin, C. D. Wood, N. L. Campbell,
H. Niu, C. Dickinson, A. Y. Ganin, M. J. Rosseinsky, Y. Z.
4
mol% Fe-porphyrins, r.t.) in the literature, which may result
from the short diffusion pathway of substrates and good
dispersion ability of H-MFePN.
7
3
(
a)
3
4
Khimyak and A. I. Cooper, Angew. Chem., Int. Ed. 2007, 46
8
,
574-8578; (b) J. –X. Jiang, F. Su, A. Trewin, C. D. Wood, H.
Niu, J. T. A. Jones, Y. Z. Khimyak and A. I. Cooper, J. Am.
Chem. Soc. 2008, 130, 7710-7720.
(a) J. R. Holst, E. Stöckel, D. J. Adams and A. I. Cooper,
Macromolecules 2010, 43, 8531-8538; (b) O. Plietzsch, C. I.
Schilling, T. Grab, S. L. Grage, A. S. Ulrich, A. Comotti, P.
Sozzani, T. Muller and S. Br
581; (c) P. Pandy, O. K. Farha, A. M. Spokoyny, C. A. Mirkin,
M. G. Kanatzidis, J. T. Hupp and S. T. Nguyen, J. Mater. Chem.
äse, New J. Chem. 2011, 35, 1577-
1
(
b)
Before (c)
After
2
011, 21, 1700-1703; (d) L. Li, H. Zhao and R. Wang, ACS Catal.
015, , 948-955; (e) H. Zhong, C. Liu, Y. Wang, R. Wang and
, 2188-2194; (f) L. Li, C. Cui, W.
Su, Y. Wang and R. Wang, Nano. Res. 2016, , 779-786.
2
5
M. Hong, Chem. Sci. 2016,
7
9
5
(a) N. Kang, J. H. Park, M. Jin, N. Park, S. M. Lee, H. J. Kim, J.
M. Kim and S. U. Son, J. Am. Chem. Soc. 2013, 135, 19115-
1
9118; (b) J. Chun, S. Kang, N. Park, E. J. Park, X. Jin, K. –D.
200 nm
200 nm
Kim, H. O. Seo, S. M. Lee, H. J. Kim, W. H. Kwon, Y. –K. Park,
J. M. Kim, Y. D. Kim and S. U. Son, J. Am. Chem. Soc. 2014,
(
d)
(e)
1
36, 6786-6789; (c) S. Kang, J. Chun, N. Park, S. M. Lee, H. J.
Kim and S. U. Son, Chem. Commun. 2015, 51, 11814-11817.
6
7
(a) A. Laybourn, R. Dawson, R. Clowes, T. Hasell, A. I. Cooper,
After
Y. Z. Khimyak and D. J. Adams, Polym. Chem. 2014,
333; (b) B. Kim, N. Park, S. M. Lee, H. J. Kim and S. U. Son,
Polym. Chem. 2015, , 7363-7367.
5, 6325-
After
6
Fe 2p3/2
Fe 2p1/2
6
(a) N. Park, Y. N. Lim, S. Y. Kang, S. M. Lee, H. J. Kim, Y. –J.
Ko, B. Y. Lee, H. –Y. Jang and S. U. Son, ACS Macro Lett. 2016,
Before
Before
5
, 1322-1326; (b) J. H. Ko, N. Kang, N. Park, H. –W. Shin, S.
Kang, S. M. Lee, H. J. Kim, T. K. Ahn and S. U. Son, ACS
Macro Lett. 2015, , 669-672.
4
8
9
M. B. Gawande, A. Goswami, F. –X. Felpin, T. Asefa, X. Huang,
R. Silva, X. Zhou, R. Zboril and R. S. Varma, Chem. Rev. 2016,
Fig. 4 (a) Recycle tests (Entries 7‐11 in Table 1) of H‐MFePN
catalysts in the reaction of EDA with aniline. (b) SEM images, XPS,
and absorption spectra of H‐MFePN before and after five catalytic
cycles.
1
16, 3722-3811.
I. –C. Chang, P. –C. Chen, M. –C. Tsai, T. –T. Chen, M. –H.
Yang, H. –T. Chiu and C. –Y. Lee, CrystEngComm 2013, 15
363-2366.
In conclusion, this study introduces the efficient synthetic 10 K. Chanda, S. Rej and M. H. Huang, Chem. Eur. J. 2013, 19
,
,
2
1
6036-16043 2
1 Z. –C. Sun, Y. -B. She, Y. Zhou, X. –F. Song and K. Li,
Molecules 2011 16, 2960-2970.
2 M. Jahan, Q. Bao and K. P. Loh, J. Am. Chem. Soc. 2012, 134
707-6713.
strategy for the shape-controlled MON materials, in which
hollow and microporous Fe-porphyrin networks were
1
1
,
successfully engineered utilizing Cu O nanocubes as templates
2
,
and networking catalysts. We believe that this synthetic
6
strategy is extendable to more various hollow and functional 13 K. M. Kadish, L. A. Bottomley, J. G. Brace and N. Winograd, J.
Am. Chem. Soc. 1980, 102, 4341-4344.
4 K. Gopalaiah, Chem. Rev. 2013, 113, 3248-3296.
MONs through screening of the tailored building blocks.
1
Acknowledgements
15 (a) L. K. Baumann, H. M. Mbuvi, G. Du and L. K. Woo,
Organometallics 2007, 26, 3995-4002; (b) I. Aviv and Z. Gross,
This research was supported by Basic Science Research Program
Synlett 2006,
6, 951; (c) I. Aiv and Z. Gross, Chem. Eur. J. 2008,
(
2016R1E1A1A01941074) through the NRF of Korea funded by the
1
4
, 3995-4005.
Ministry of Science, ICT and Future Planning.
1
1
6 D. A. Sharon, D. Mallick, B. Wang and S. Shaik, J. Am. Chem.
Soc. 2016, 138, 9597-9610.
7 (a) J. Yoo, N. Park, J. H. Park, J. H. Park, S. Kang, S. M. Lee, H.
Notes and references
1
Reviews: (a) Y. Xu, S. Jin, H. Xu, A. Nagai and D. Jiang, Chem.
Soc. Rev. 2013, 42, 8012-8031; (b) R. Dawson, A. I. Cooper and
D. J. Adams, Prog. Poly. Sci. 2012, 37, 530-563; (c) F. Vilela, K.
J. Kim, H. Jo, J. -G. Park and S. U. Son, ACS Catalysis 2015,
50-355; (b) L. Xu, M. –K. Zhai, F. Wang, L. Sun and H. –B. Du,
Dalton Trans. 2016, 45, 17108-17112.
5,
3
Zhang and M. Antonietti, Energy Environ. Sci. 2012,
5, 7819-
4
| J. Name., 2012, 00, 1‐3
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