Chemistry Letters p. 1675 - 1678 (1987)
Update date:2022-08-22
Topics:
Yoneda, Norihiko
Fukuhara, Tsuyoshi
Yamagishi, Ken
Suzuki, Akira
Deep purplish red semicrystalline precipitates were obtained by the treatment of Cu2O with HF.After calcination at 100 deg C or higher temperature, this compound was successfully used as a highly effective halogen-exchange fluorination reagent for primary alkyl halides in the presence of pyridine derivatives.AgF and a mixture of CuF2 with copper powder also exhibited high activity in the reaction.
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