3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine

Base Information

• Chemical Name: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine
• CAS No.: 30556-86-6
• Molecular Formula: C8H6F13N
• Molecular Weight: 363.122
• Hs Code.: 2921199090
• DSSTox Substance ID: DTXSID40439436
• Nikkaji Number: J25.721D
• Wikidata: Q82255388
• Mol file: 30556-86-6.mol

Synonyms:1-Octanamine,3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro;3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine;1H,1H,2H,2H-perfluorooctylamine;

Chemical Property of 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine

Chemical Property:

• PSA: 26.02000
• LogP: 4.77430
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 6
• Exact Mass: 363.0292653
• Heavy Atom Count: 22
• Complexity: 395

Purity/Quality:

99%, ^*data from raw suppliers

1H,1H,2H,2H-Perfluorooctylamine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(CN)C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine

There total 2 articles about 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

8-azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooctane (62571-55-5) → 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine (30556-86-6)

Guidance literature:

With hydrogen; palladium on activated charcoal; In diethyl ether; at 20 ℃; under 5171.62 Torr;

DOI:10.1021/ol016165+

Reference yield:

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane (2043-57-4,71215-70-8) → 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine (30556-86-6)

Guidance literature:

With sodium azide; N₂H₄*H₂O-Raney Ni; hydrazine hydrate; Multistep reaction;

DOI:10.1080/00397919708004170

Reference yield: 98.0%

isocyanate de chloro-4 phenoxysulfonyle (14793-41-0) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine (30556-86-6) → C15H10ClF13N2O4S

Guidance literature:

In toluene; at 0 ℃; for 0.0833333h;

DOI:10.1016/S0022-1139(98)00309-1

upstream raw materials:

8-azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooctane

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane

Downstream raw materials:

Benzyl-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-amine

Refernces

• 1、 Raghavanpillai, Anilkumar,Franco, Vincent A.,Meredith, Walter E.. "Hydrophobic and oleophobic surface modification using gelling agents derived from amino acids". . p. 187 - 194. Retrieved 2012.
• 2、 Roman,Szoenyi,Bracon,Cambon. "An effective route to N,N-Bis (2,3-epoxypropyl)2-F-alkylethylamines". . p. 3125 - 3132. Retrieved 1997.
• 3、 -. "Synthetic method of N-(1H,1H,2H,2H-perfluorinated octyl) acrylamide". Paragraph 0026; 0027; 0033; 0034; 0040; 0041. . Retrieved 2017/08/25.
• 4、 Massi, Lionel,Guittard, Frederic,Levy, Richard,Geribaldi. "Enhanced activity of fluorinated quaternary ammonium surfactants against Pseudomonas aeruginosa". experimental part. p. 1615 - 1622. Retrieved 2009/06/20.