Diethylbutylamine

Base Information

• Chemical Name: Diethylbutylamine
• CAS No.: 4444-68-2
• Molecular Formula: C8H19 N
• Molecular Weight: 129.246
• Hs Code.: 2921199090
• European Community (EC) Number: 623-584-4
• UN Number: 2733
• DSSTox Substance ID: DTXSID9025039
• Nikkaji Number: J121.776C
• Wikidata: Q72469218
• Mol file: 4444-68-2.mol

Synonyms:N,N-diethylbutan-1-amine;4444-68-2;DIETHYLBUTYLAMINE;N,N-Diethylbutylamine;1-Butanamine, N,N-diethyl-;Butylamine, N,N-diethyl-;CCRIS 6017;N,N-Diethyl-1-butanamine;butyldiethylamine;Diethyl n-butylamine;SCHEMBL22725;N,N-Diethylbutylamine, 97%;Ethanamine, N-butyl-N-ethyl-;DTXSID9025039;ORSUTASIQKBEFU-UHFFFAOYSA-N;ADAL1185601;AMY13335;AKOS000120687;LS-1265;SB75553;AS-78565;CS-0152122;FT-0693119;D94767

Chemical Property of Diethylbutylamine

Chemical Property:

• Vapor Pressure: 5.98mmHg at 25°C
• Melting Point: 136-137℃
• Refractive Index: n20/D 1.414(lit.)
• Boiling Point: 141°Cat760mmHg
• Flash Point: 26.8°C
• PSA: 3.24000
• Density: 0.77g/cm³
• LogP: 2.12830
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 129.151749610
• Heavy Atom Count: 9
• Complexity: 48.5
• Transport DOT Label: Flammable Liquid Corrosive

Purity/Quality:

98%,99%, ^*data from raw suppliers

N,N-Diethylbutylamine 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 10-34
• Safety Statements: 16-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN(CC)CC
• Uses: N,N-Diethylbutylamine may be used for the regioselective syntheses of of 6-(1,1-dimethylallyl) ortho-flavones. It was used in the synthesis of N,N-diethylbutylammonium bis(trifluoromethylsulfonyl)imide.

Technology Process of Diethylbutylamine

There total 10 articles about Diethylbutylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.7%

ethylamine (75-04-7,85404-22-4) + N-butylamine (109-73-9,85404-21-3) → tributyl-amine (102-82-9) + N-ethylbutylamine (13360-63-9) + N,N-diethylbutylamine (4444-68-2) + di-n-butylethylamine (4458-33-7) + dibutylamine (111-92-2) + diethylamine (109-89-7) + triethylamine (121-44-8)

Guidance literature:

With hydrogen; at 200 ℃; under 6000.6 Torr; Reagent/catalyst; Temperature;

DOI:10.1007/s11164-012-0790-8

Reference yield:

ethylamine (75-04-7,85404-22-4) + crotonaldehyde (123-73-9,4170-30-3) → N-ethylbutylamine (13360-63-9) + N,N-diethylbutylamine (4444-68-2)

Guidance literature:

With methanol; nickel; at 125 ℃; Hydrogenation;

Reference yield:

diethyl ether (60-29-7,927820-24-4) + N-butylamine (109-73-9,85404-21-3) → N-ethylbutylamine (13360-63-9) + N,N-diethylbutylamine (4444-68-2)

Guidance literature:

With alumina; at 300 ℃; under 760.051 Torr; Temperature; Inert atmosphere; Gas phase; Green chemistry;

DOI:10.2478/s11696-010-0033-7

upstream raw materials:

ethylamine

crotonaldehyde

ethyllithium

butyltriethylammonium hydrogen sulfate

Downstream raw materials:

butyltriethylammonium hydrogen sulfate

N-(n-butyl)aniline

N-ethyl-N-phenylamine

(E)-N'-((4-methylphenyl)sulfonyl)-N,N-diethylformimidamide

Refernces

• 1、 Xu, Lu-Feng,Huang, Jia-Min,Qian, Chao,Chen, Xin-Zhi,Feng, Lie,Chen, Yun-Bin,He, Chao-Hong. "The synthesis of N-ethyl-n-butylamine by amines disproportionation". . p. 2697 - 2704. Retrieved 2013/07/26.