Carbonic acid, mono(phenylmethyl) ester, sodium salt

Base Information

• Chemical Name: Carbonic acid, mono(phenylmethyl) ester, sodium salt
• CAS No.: 61668-49-3
• Molecular Formula: C8H8O3.Na
• Molecular Weight: 174.132
• Mol file: 61668-49-3.mol

Synonyms:

Chemical Property of Carbonic acid, mono(phenylmethyl) ester, sodium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbonic acid, mono(phenylmethyl) ester, sodium salt

There total 1 articles about Carbonic acid, mono(phenylmethyl) ester, sodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + benzyl alcohol (100-51-6,185532-71-2) → sodium benzylcarbonate (61668-49-3)

Guidance literature:

With sodium hydride; Multistep reaction; 1) THF, reflux, 2h, 2) room temperature, 1h;

DOI:10.1016/S0040-4039(00)85214-4

Reference yield: 70.0%

C21H23NO6S (178866-96-1) + sodium benzylcarbonate (61668-49-3) → C28H27NO6

Guidance literature:

In dimethyl sulfoxide; at 20 - 90 ℃;

Reference yield: 53.0%

sodium benzylcarbonate (61668-49-3) + benzyl chloroformate (501-53-1,94274-21-2) → dibenzyl dicarbonate (31139-36-3)

Guidance literature:

for 8h; Ambient temperature;

upstream raw materials:

carbon dioxide

benzyl alcohol

Downstream raw materials:

dibenzyl dicarbonate

N-(benzyloxycarbonyl)-L-serine

N-Cbz-L-Phe

N-benzyloxycarbonyl-L-treonine

Refernces