Trichlorocyclopentylsilane

Base Information

• Chemical Name: Trichlorocyclopentylsilane
• CAS No.: 14579-03-4
• Molecular Formula: C5H9Cl3Si
• Molecular Weight: 203.571
• Hs Code.: 2931900090
• European Community (EC) Number: 238-621-6
• DSSTox Substance ID: DTXSID9065788
• Nikkaji Number: J241.314K
• Wikidata: Q81992399
• Mol file: 14579-03-4.mol

Synonyms:14579-03-4;CYCLOPENTYLTRICHLOROSILANE;Trichlorocyclopentylsilane;trichloro(cyclopentyl)silane;Cyclopentane, (trichlorosilyl)-;Silane, trichlorocyclopentyl-;EINECS 238-621-6;Trichlorcyclopentylsilane;C5H9Cl3Si;Trichlorosilylcyclopentane;cyclopentyl trichlorosilane;C5-H9-Cl3-Si;SCHEMBL133415;Trichlorocyclopentylsilane, 95%;DTXSID9065788;AMY37146;MFCD00236508;FT-0624273;T2576;D92617

Chemical Property of Trichlorocyclopentylsilane

Chemical Property:

• Vapor Pressure: 1.18mmHg at 25°C
• Refractive Index: n20/D 1.469(lit.)
• Boiling Point: 181.1 °C at 760 mmHg
• Flash Point: 74.8 °C
• PSA: 0.00000
• Density: 1.24 g/cm³
• LogP: 3.58590
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 201.953910
• Heavy Atom Count: 9
• Complexity: 92.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trichlorocyclopentylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CCC(C1)[Si](Cl)(Cl)Cl
• Uses: Trichloro(cyclopentyl)silane can be used in the preparation of POSS by hydrolysis and condensation reaction that is majorly used to enhance the thermo-mechanical properties of different polymers.

Technology Process of Trichlorocyclopentylsilane

There total 16 articles about Trichlorocyclopentylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

cyclopentene (142-29-0) → trichloro(cyclopentyl)silane (14579-03-4)

Guidance literature:

With trichlorosilane; at 250 ℃; for 6h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2011.08.019

Reference yield: 91.0%

→ trichloro(cyclopentyl)silane (14579-03-4)

Guidance literature:

Reference yield: 78.0%

→ tert-amyloxy cyclopentyl dimethoxysilane (149184-17-8) + trichloro(cyclopentyl)silane (14579-03-4)

Guidance literature:

upstream raw materials:

acetone

cyclopentene

cyclopentylmagnesium chloride

Downstream raw materials:

cyclopentyl trimethoxysilane

dichloro(cyclopentyl)(methyl)silane

4-(cyclopentyl)-benzonitrile

C₄₁H₆₈O₁₂Si₈

Refernces

• 1、 Jung, Dong Euy,Han, Joon Soo,Yoo, Bok Ryul. "Thermal hydrosilylation of olefin with hydrosilane. Preparative and mechanistic aspects". experimental part. p. 3687 - 3692. Retrieved 2011/11/29.
• 2、 Yarosh,Mirskov,Yarosh,Albanov,Voronkov. "Organosilicon derivatives of cyclopentane". . p. 242 - 244. Retrieved 2007/10/03.