Cyclohexyltrichlorosilane

Base Information

• Chemical Name: Cyclohexyltrichlorosilane
• CAS No.: 98-12-4
• Molecular Formula: C6H11 Cl3 Si
• Molecular Weight: 217.598
• Hs Code.: 2931900090
• European Community (EC) Number: 202-639-2
• UN Number: 1763
• UNII: 3J37567BD2
• DSSTox Substance ID: DTXSID0059160
• Nikkaji Number: J36.475D
• Wikidata: Q27257278
• Mol file: 98-12-4.mol

Synonyms:CYCLOHEXYLTRICHLOROSILANE;Trichloro(cyclohexyl)silane;98-12-4;Silane, trichlorocyclohexyl-;Trichlorocyclohexylsilane;Cyclohexane, (trichlorosilyl)-;cyclohexyl trichlorosilane;UNII-3J37567BD2;Cyclohexane, 1-(trichlorosilyl)-;EINECS 202-639-2;UN1763;3J37567BD2;Trichlorocyclohexyl silane;C6H11Cl3Si;Silane, cyclohexyltrichloro-;C6-H11-Cl3-Si;SCHEMBL133902;1-(Trichlorosilyl) cyclohexane;Trichlorocyclohexylsilane, 98%;DTXSID0059160;HSDB 7784;(TRICHLOROSILYL)CYCLOHEXANE;MFCD00021280;NA1763;AKOS015840731;CYCLOHEXYLTRICHLOROSILANE [HSDB];FS-5437;UN 1763;FT-0624235;CyclohexyltrichlorosilaneTrichlorocyclohexysilane;D89321;S05225;Cyclohexyltrichlorosilane [UN1763] [Corrosive];Q27257278

Chemical Property of Cyclohexyltrichlorosilane

Chemical Property:

• Appearance/Colour: CLEAR COLOURLESS LIQUID
• Vapor Pressure: 0.465mmHg at 25°C
• Refractive Index: n20/D 1.478(lit.)
• Boiling Point: 200.2°Cat760mmHg
• Flash Point: 87°C
• PSA: 0.00000
• Density: 1.2g/cm³
• LogP: 3.97600
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 215.969560
• Heavy Atom Count: 10
• Complexity: 104
• Transport DOT Label: Corrosive

Purity/Quality:

98%, ^*data from raw suppliers

Cyclohexyltrichlorosilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Toxic by ingestion and inhalation, strong irritant to tissue.
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CCC(CC1)[Si](Cl)(Cl)Cl

Technology Process of Cyclohexyltrichlorosilane

There total 12 articles about Cyclohexyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

cyclohexene (110-83-8) → cyclohexyltrichlorosilane (98-12-4)

Guidance literature:

With trichlorosilane; at 250 ℃; for 6h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2011.08.019

Reference yield: 64.4%

trichlorosilane (10025-78-2) + cyclohexene (110-83-8) → cyclohexyltrichlorosilane (98-12-4)

Guidance literature:

In neat (no solvent); HSiCl3 and cyclohexene at 80°C in presence of (CH3CO)2O;;

DOI:10.1021/ja01203a039

Reference yield:

cyclohexa-1,4-diene (1165952-92-0) → cyclohexyltrichlorosilane (98-12-4) + trichloro(cyclohex-3-en-1-yl)silane (10137-69-6) + (+/-)-3-trichlorosilylcyclohexene (18139-74-7) + cyclohexene (110-83-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

With trichlorosilane; In dodecane; at 250 ℃; for 4h; Temperature; Time; Inert atmosphere;

DOI:10.1016/j.jorganchem.2012.10.015

upstream raw materials:

cyclohexane

cyclohexylmagnesium bromide

cyclohexene

cyclohexylmagnesiumchloride

Downstream raw materials:

triacetoxy-cyclohexyl-silane

cyclohexyl-tris-trifluoroacetoxy-silane

cyclohexyl-triisocyanato-silane

Methyltrichlorosilane

Refernces

• 1、 Jung, Dong Eui,Han, Joon Soo,Yoo, Bok Ryul. "Thermal reaction of cyclic alkadiene with trichlorosilane. Preparative and mechanistic aspects". . p. 40 - 44. Retrieved 2013/03/13.
• 2、 Belyakova,Chernyshev,Storozhenko,Knyazev,Turkel'taub,Parshina,Kisin. "Hydrosilylation of cyclohexene and allyl chloride with trichloro-, dichloro(methyl)-, and chlorodimethylsilanes in the presence of Pt(0) complexes". . p. 925 - 930. Retrieved 2008/02/03.