N-(dibutyl-lambda(4)-sulfanylidene)-4-methylbenzenesulfonamide

Base Information

• Chemical Name: N-(dibutyl-lambda(4)-sulfanylidene)-4-methylbenzenesulfonamide
• CAS No.: 17627-00-8
• Molecular Formula: C15H25 N O2 S2
• Molecular Weight: 315.501
• NSC Number: 99884
• DSSTox Substance ID: DTXSID60938779
• Wikidata: Q82915187
• Mol file: 17627-00-8.mol

Synonyms:17627-00-8;NSC99884;DTXSID60938779;NSC-99884;N-(dibutyl-lambda(4)-sulfanylidene)-4-methylbenzenesulfonamide;N-(Dibutyl-lambda~4~-sulfanylidene)-4-methylbenzene-1-sulfonamide

Chemical Property of N-(dibutyl-lambda(4)-sulfanylidene)-4-methylbenzenesulfonamide

Chemical Property:

• Vapor Pressure: 3.91E-08mmHg at 25°C
• Boiling Point: 457.9°Cat760mmHg
• Flash Point: 230.7°C
• Density: 1.12g/cm³
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 315.13267139
• Heavy Atom Count: 20
• Complexity: 381

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCS(=NS(=O)(=O)C1=CC=C(C=C1)C)CCCC

Technology Process of N-(dibutyl-lambda(4)-sulfanylidene)-4-methylbenzenesulfonamide

There total 3 articles about N-(dibutyl-lambda(4)-sulfanylidene)-4-methylbenzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Dibutyl sulfide (544-40-1) + [N-(p-tolylsulfonyl)imino]phenyliodinane (55962-05-5) → S,S-dibutyl-N-p-tosylsulfilimine (17627-00-8)

Guidance literature:

Cu(3,4,7,8-tetramethyl-1,10-phenanthroline)(PPh₃)Br; In acetonitrile; at 20 ℃; for 0.5h;

DOI:10.1080/00397910701798200

Reference yield:

Dibutyl sulfide (544-40-1) + N-bromo-N-potassio-p-toluenesulfonamide (70284-20-7) → butyl sulfoxide (2168-93-6) + S,S-dibutyl-N-p-tosylsulfilimine (17627-00-8) + toluene-4-sulfonamide (70-55-3)

Guidance literature:

With Britton-Robinson buffer; In methanol; water; at 20 ℃; Rate constant; Mechanism; Product distribution; NaOH, pH = 12.70; also in unbuffered solution;

Reference yield:

Dibutyl sulfide (544-40-1) + chloroamine-T (127-65-1) → S,S-dibutyl-N-p-tosylsulfilimine (17627-00-8)

Guidance literature:

With ethanol;

DOI:10.1021/ja01243a015

upstream raw materials:

Dibutyl sulfide

chloroamine-T

N-bromo-N-potassio-p-toluenesulfonamide

[N-(p-tolylsulfonyl)imino]phenyliodinane

Downstream raw materials:

Dibutyl sulfide

dibutyl disulfide

n-butyl 4-methylphenyl sulfide

4-methylphenyl n-butyl disulfide

Refernces

• 1、 Giribabu,Singh, Surya P.,Patil, Nandkumar M.,Kantam, M. Lakshmi,Gupte, Sunil P.,Chaudhari, Raghunath V.. "Highly efficient sulfimidation of 1,3-dithianes by Cu(I) complexes". . p. 619 - 625. Retrieved 2008/04/12.