2,2'-Bipyridine, 1,1'-dioxide

Base Information Edit

Chemical Name:2,2'-Bipyridine, 1,1'-dioxide
CAS No.:7275-43-6
Molecular Formula:C10H8N2O2
Molecular Weight:188.186
Hs Code.:29333999
European Community (EC) Number:625-380-0
NSC Number:351883
UNII:WE8HPX9ZYR
Nikkaji Number:J357.898D
Wikidata:Q72469513
Mol file:7275-43-6.mol

Synonyms:7275-43-6;2,2'-Dipyridyl N,N'-dioxide;2,2'-Bipyridine 1,1'-dioxide;2,2'-Bipyridyl 1,1'-Dioxide;[2,2'-Bipyridine] 1,1'-dioxide;2,2'-BIPYRIDINE, 1,1'-DIOXIDE;2,2'-Dipyridyl dioxide;NSC 351883;MFCD00065169;2-(1-oxidopyridin-2-ylidene)pyridin-1-ium 1-oxide;2,2'-bipyridine n,n'-dioxide;NSC-351883;[2,2'-BIPYRIDINE]-1,1'-DIIUM-1,1'-BIS(OLATE);[2,2 inverted exclamation mark -Bipyridine] 1,1 inverted exclamation mark -Dioxide;WE8HPX9ZYR;bipyridine N,N'-dioxide;3-Chloro Benzyl Cyanide;SCHEMBL871319;2,2'-Bipyridine di-N-oxide;2-(1-oxidopyridin-1-ium-2-yl)pyridin-1-ium-1-olate;2,2'-Bipyridine1,1'-dioxide;2,2'-Dipyridyl-N,N'-dioxide;YSSJ00810;[2,2'-Bipyridine]1,1'-dioxide;2,2-DIPYRIDYL N,N-DIOXIDE;NSC351883;2,2'-Bipyridyl-1,1'-di-N-oxide;AKOS000271616;2,2'-Dipyridyl N,N'-dioxide, 98%;2,2\'-DIPYRIDYL N,N\'-DIOXIDE;LS-44632;SY060046;B3859;D83797;A866208;SR-01000517700;SR-01000517700-1;1-oxido-2-(1-oxidopyridin-1-ium-2-yl)pyridin-1-ium

Suppliers and Price of 2,2'-Bipyridine, 1,1'-dioxide

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,2'-Bipyridyl 1,1'-Dioxide
100mg
$ 60.00

TRC
2,2'-Bipyridyl 1,1'-Dioxide
50mg
$ 45.00

TRC
2,2'-Bipyridyl 1,1'-Dioxide
500mg
$ 75.00

TCI Chemical
2,2'-Bipyridyl 1,1'-Dioxide >98.0%(HPLC)(T)
5g
$ 117.00

Sigma-Aldrich
2,2′-Dipyridyl N,N′-dioxide 98%
1g
$ 43.80

Chem-Impex
2,2'-Bipyridyl1,1'-dioxide,≥98%(HPLC) ≥98%(HPLC)
5G
$ 157.25

Biosynth Carbosynth
2,2'-Bipyridyl 1,1'-Dioxide
25 g
$ 334.00

Biosynth Carbosynth
2,2'-Bipyridyl 1,1'-Dioxide
50 g
$ 568.00

Biosynth Carbosynth
2,2'-Bipyridyl 1,1'-Dioxide
10 g
$ 167.00

American Custom Chemicals Corporation
2,2′-Dipyridyl N,N′-dioxide 95.00%
1G
$ 651.61

Total 32 raw suppliers

Chemical Property of 2,2'-Bipyridine, 1,1'-dioxide Edit

Chemical Property:

Appearance/Colour:off-white to cream powder
Melting Point:296-298 °C(lit.)
Refractive Index:1.5910 (estimate)
Boiling Point:296-298 °C(lit.)
PKA:-1.34±0.10(Predicted)
PSA：50.92000
Density:1.2577 (rough estimate)
LogP:2.21060
Storage Temp.:Inert atmosphere,Room Temperature
Water Solubility.:Soluble in water
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:188.058577502
Heavy Atom Count:14
Complexity:376

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,2'-Bipyridyl 1,1'-Dioxide ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Nitrogen Compounds -> Pyridines
Canonical SMILES:C1=CC(=C2C=CC=C[N+]2=O)N(C=C1)[O-]

Technology Process of 2,2'-Bipyridine, 1,1'-dioxide

There total 5 articles about 2,2'-Bipyridine, 1,1'-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.6%

: 366-18-7
[2,2]bipyridinyl

: 7275-43-6
[2,2']bipyridinyl 1,1'-dioxide

Guidance literature:: With phthalic anhydride; urea-hydrogen peroxide; In dichloromethane; for 24h; Ambient temperature;

Reference yield: 89.4%

: 366-18-7
[2,2]bipyridinyl

: 33421-43-1
2,2'-bipyridyl N-oxide

: 7275-43-6
[2,2']bipyridinyl 1,1'-dioxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In chloroform; at 20 ℃; for 21.3h;
DOI:10.1016/j.tetlet.2013.07.150

Reference yield: 43.0%

: 694-59-7
pyridine N-oxide

: 7275-43-6
[2,2']bipyridinyl 1,1'-dioxide

Guidance literature:: With 1,10-Phenanthroline; potassium tert-butylate; palladium diacetate; silver carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 24h; regioselective reaction;
DOI:10.1016/j.tetlet.2016.10.032