5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE

Base Information

• Chemical Name: 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE
• CAS No.: 16834-13-2
• Molecular Formula: C40H26N8
• Molecular Weight: 618.7
• Hs Code.: 29333990
• Mol file: 16834-13-2.mol

Synonyms:Porphine,5,10,15,20-tetra-4-pyridyl- (6CI,8CI);Porphine, a,b,g,d-tetra-4-pyridyl- (7CI);5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine;5,10,15,20-Tetra(4-pyridyl)porphyrin;5,10,15,20-Tetrakis(4-pyridinyl)-21H,23H-porphine;5,10,15,20-Tetrakis(4-pyridyl)-21H,23H-porphyrin;5,10,15,20-Tetrakis(4-pyridyl)porphyrin;5,10,15,20-Tetrakis(4'-N-pyridyl)porphyrin;Mesotetra(4-pyridyl)porphyrin;Tetra(4-pyridyl)porphine;Tetra(4-pyridyl)porphyrin;Tetrakis(4-pyridyl)porphine;Tetrakis(4-pyridyl)porphyrin;meso-Tetra(4-pyridyl)porphyrin;meso-Tetrakis(4-pyridyl)porphine;a,b,g,d-Tetra-4-pyridylporphine;a,b,g,d-Tetrakis(4-pyridyl)porphine;

Chemical Property of 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE

Chemical Property:

• Refractive Index: 1.711
• PSA: 107.86000
• Density: 1.352 g/cm³
• LogP: 4.44620
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine is used in the making of coordination catalysts.

Technology Process of 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE

There total 31 articles about 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

pyridine-4-carbaldehyde (872-85-5) + pyrrole (109-97-7,30604-81-0) → 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (16834-13-2)

Guidance literature:

With propionic acid; for 3h; Reflux; Darkness;

DOI:10.1039/c7ta06658a

Reference yield: 27.0%

1-isonicotinoyl-5-(4-pyridyl)dipyrromethane (1046493-91-7) + 5-formyl-2,2'-dipyrrylmethane (36746-27-7) → 5,10-di(4-pyridyl)porphyrin + porphyrin (101-60-0) + 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (16834-13-2)

Guidance literature:

With air; 1,8-diazabicyclo[5.4.0]undec-7-ene; magnesium bromide; In toluene; at 115 ℃; for 1.5h; microwave irradiation;

DOI:10.1021/jo800588n

Reference yield: 26.0%

1-isonicotinoyl-5-(4-pyridyl)dipyrromethane (1046493-91-7) + 1-hexanoyl-5-pentyldipyrromethane (749923-26-0) → 5,10-dipentyl-15,20-di(4-pyridyl)porphyrin + 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (16834-13-2)

Guidance literature:

With air; 1,8-diazabicyclo[5.4.0]undec-7-ene; magnesium bromide; In toluene; at 115 ℃; for 2h; microwave irradiation;

DOI:10.1021/jo800588n

upstream raw materials:

pyridine-4-carbaldehyde

pyrrole

caprinaldehyde

benzo-15-crown-5-ether

Downstream raw materials:

dichloro-(5,10,15,20-tetrakis-(4-pyridyl)-porphyrinato)tin(IV)

5,10,15,20-tetrakis(4-methylpyridinium)porphyrin tetrahydrochloride

5,10,15,20-tetrakis(4-pyridyl)porphyrin zinc(II)

5,10,15,20-tetra(4-pyridyl)porphyrin zinc

Refernces

• 1、 Oliveras-González, Cristina,Di Meo, Florent,González-Campo, Arántzazu,Beljonne, David,Norman, Patrick,Simón-Sorbed, Maite,Linares, Mathieu,Amabilino, David B.. "Bottom-Up Hierarchical Self-Assembly of Chiral Porphyrins through Coordination and Hydrogen Bonds". . p. 15795 - 15808. Retrieved 2015.
• 2、 Zhang, Huidong,Sun, Yinghui,Ye, Kaiqi,Zhang, Ping,Wang, Yue. "Oxygen sensing materials based on mesoporous silica MCM-41 and Pt(II)-porphyrin complexes". . p. 3181 - 3186. Retrieved 2005.
• 3、 Hu, Xiaojun,Ogawa, Kazuma,Li, Siqiaozhi,Kiwada, Tatsuto,Odani, Akira. "A platinum functional porphyrin conjugate: An excellent cancer killer for photodynamic therapy". . p. 790 - 796. Retrieved 2019.
• 4、 Ghafuri, Hossein,Mohammadi, Fatemeh,Rahimi, Rahmatallah,Mohammadiyan, Esmaeel. "Synthesis and characterization of a new magnetic nanocomposite with metalloporphyrin (Co-TPyP) and sulfated tin dioxide (Fe3O4@SnO2/SO42-), and investigation of its photocatalytic effects in the degradation of Rhodamine B". . p. 83947 - 83953. Retrieved 2016.
• 5、 Ovchenkova,Bichan,Lyubimtsev,Garasko,Lomova. "Synthesis and Antimicrobial Activity of a Pyridine Complex of (Acetato)[5,10,15,20-tetrakis(N-methylpyridin- 4-yl)porphinato]manganese(III) Tetratosylate". . p. 1657 - 1662. Retrieved 2018.
• 6、 Guleria, Mohini,Suman, Shishu K.,Mitra, Jyotsna B.,Shelar, Sandeep B.,Amirdhanayagam, Jeyachitra,Sarma, Haladhar D.,Dash, Ashutosh,Das, Tapas. "Effect of structural variation on tumor targeting efficacy of cationically charged porphyrin derivatives: Comparative in-vitro and in-vivo evaluation for possible potential in PET and PDT". . . Retrieved 2021.
• 7、 Tomé, Jo?o P. C.,Neves, Maria G. P. M. S.,Tomé, Augusto C.,Cavaleiro, José A. S.,Soncin, Marina,Magaraggia, Michela,Ferro, Stefania,Jori, Giulio. "Synthesis and antibacterial activity of new poly-S-lysine-porphyrin conjugates". . p. 6649 - 6652. Retrieved 2004.
• 8、 Lin, Qipu,Mao, Chengyu,Kong, Aiguo,Bu, Xianhui,Zhao, Xiang,Feng, Pingyun. "Porphyrinic coordination lattices with fluoropillars". . p. 21189 - 21195. Retrieved 2017.
• 9、 Zhao, Ping,Liu, Min-Chao,Madanayake, Thushara W.,Reena, Chawla,Zheng, Min,Cheng, Zhen-Feng,Huang, Yu-Min,Wang, Xia-Hong. "Cationic porphyrin@SPION nanospheres as multifunctional anticancer therapeutics: Magnetic targeting, photodynamic potential and bio-safety research". . p. 103137 - 103148. Retrieved 2016.
• 10、 Liu, Shengda,Tian, Ruizhen,Xu, Jiayun,Wang, Liang,Sun, Jianxin,Jiang, Xiaojia,Wang, Tingting,Li, Xiumei,Luo, Quan,Liu, Junqiu. "Cucurbit[8]uril-based supramolecular nanocapsules with a multienzyme-cascade antioxidative effect". . p. 13820 - 13823. Retrieved 2019.