2-Phenoxyethyl carbonate(2:1)

Base Information

• Chemical Name: 2-Phenoxyethyl carbonate(2:1)
• CAS No.: 22855-36-3
• Molecular Formula: C17H18 O5
• Molecular Weight: 302.327
• European Community (EC) Number: 245-267-6
• NSC Number: 68849
• DSSTox Substance ID: DTXSID50177397
• Nikkaji Number: J286.325A
• Wikidata: Q83047727
• Mol file: 22855-36-3.mol

Synonyms:2-Phenoxyethyl carbonate(2:1);22855-36-3;EINECS 245-267-6;NSC68849;SCHEMBL4900332;DTXSID50177397;NSC 68849;NSC-68849;Carbonic acid bis(2-phenoxyethyl) ester

Chemical Property of 2-Phenoxyethyl carbonate(2:1)

Chemical Property:

• Vapor Pressure: 9.77E-08mmHg at 25°C
• Boiling Point: 434.1°C at 760 mmHg
• Flash Point: 191.4°C
• Density: 1.173g/cm³
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 10
• Exact Mass: 302.11542367
• Heavy Atom Count: 22
• Complexity: 267

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OCCOC(=O)OCCOC2=CC=CC=C2

Technology Process of 2-Phenoxyethyl carbonate(2:1)

There total 10 articles about 2-Phenoxyethyl carbonate(2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosgene (75-44-5) + 2-Phenoxyethanol (122-99-6,56257-90-0,9004-78-8) → bis(2-phenoxyethyl)carbonate (22855-36-3) + 1-chlorocarbonyloxy-2-phenoxy-ethane (34743-87-8)

Guidance literature:

at 35 - 40 ℃;

Reference yield:

[1,3]-dioxolan-2-one (96-49-1) + phenol (108-95-2,27073-41-2) → 2-Phenoxyethanol (122-99-6,56257-90-0,9004-78-8) + bis(2-phenoxyethyl)carbonate (22855-36-3)

Guidance literature:

With sodium mordenite molecular sieve CBV 10A; at 210 ℃; for 7h; Temperature; Time; Inert atmosphere;

DOI:10.1039/c4cy00913d

Reference yield:

carbonic acid ethyl ester-(2-phenoxy-ethyl ester) (40496-06-8) → bis(2-phenoxyethyl)carbonate (22855-36-3)

Guidance literature:

With tetrabutoxytitanium; sodium; butan-1-ol; at 250 ℃;

DOI:10.1021/jo01083a020

upstream raw materials:

phosgene

2-Phenoxyethanol

carbonic acid ethyl ester-(2-phenoxy-ethyl ester)

oxirane

Downstream raw materials:

2-Phenoxyethanol

Refernces