Bisphenol A bis(2-hydroxypropyl) ether

Base Information

• Chemical Name: Bisphenol A bis(2-hydroxypropyl) ether
• CAS No.: 116-37-0
• Deprecated CAS: 144834-14-0,2088313-17-9,2099694-66-1
• Molecular Formula: C21H28O4
• Molecular Weight: 344.451
• Hs Code.: 2909499000
• European Community (EC) Number: 204-137-9
• NSC Number: 408494
• UNII: S5K2510L3D
• DSSTox Substance ID: DTXSID8051592
• Nikkaji Number: J39.711C
• Wikidata: Q27148853
• Mol file: 116-37-0.mol

Synonyms:oxypropyldiphenylolpropane

Chemical Property of Bisphenol A bis(2-hydroxypropyl) ether

Chemical Property:

• Vapor Pressure: 0Pa at 20℃
• Boiling Point: 505.4 °C at 760 mmHg
• PKA: 14.05±0.20(Predicted)
• Flash Point: 259.5 °C
• PSA: 58.92000
• Density: 1.102 g/cm³
• LogP: 3.53170
• Water Solubility.: 109mg/L at 20℃
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 344.19875937
• Heavy Atom Count: 25
• Complexity: 334

Purity/Quality:

99.9% ^*data from raw suppliers

BisphenolAbis(2-hydroxypropyl)ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Other Aromatic Compounds
• Canonical SMILES: CC(COC1=CC=C(C=C1)C(C)(C)C2=CC=C(C=C2)OCC(C)O)O
• Uses: Bisphenol A bis(2-hydroxypropyl) ether is an engineered material used as a coating for improved adhesion of aminoplasts to metals.

Technology Process of Bisphenol A bis(2-hydroxypropyl) ether

There total 5 articles about Bisphenol A bis(2-hydroxypropyl) ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

diphenylolpropane diglycidyl ether (1675-54-3,25085-99-8,55774-85-1,91384-80-4) → Bisphenol A propoxylate (116-37-0)

Guidance literature:

With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); potassium tert-butylate; hydrogen; In toluene; at 75 ℃; for 24h; under 37503.8 Torr; regioselective reaction;

DOI:10.1021/acs.orglett.9b03995

Reference yield:

BPA (80-05-7) + methyloxirane (75-56-9,16033-71-9) → Bisphenol A propoxylate (116-37-0)

Guidance literature:

BPA; With sodium hydroxide; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

methyloxirane; In tetrahydrofuran; Inert atmosphere;

Reference yield:

BPA (80-05-7) + methyloxirane (75-56-9,16033-71-9) → Bisphenol A propoxylate (116-37-0) + 4-(2-(4-(2-hydroxypropoxy)phenyl)propan-2-yl)phenol (57372-69-7) + BPA-3PO (210979-67-2)

Guidance literature:

anion exchange resin A (OH-type); In 2-methoxy-ethanol; at 100 ℃; for 6h;

upstream raw materials:

BPA

methyloxirane

propylene glycol

hydroquinone

Downstream raw materials:

2,2-Bis-[p-(2-(2-Cyano-2,4-hexadienoyl)-oxypropoxy)-phenyl]-propane

Refernces

• 1、 -. "Compositions And Methods For Bioactive Dental Composites". Paragraph 0111. . Retrieved 2016/05/24.
• 2、 Lin, Hsing-Yo,Dai, Shenghong A.. "One-pot alkoxylation of phenols with urea and 1,2-glycols". experimental part. p. 167 - 173. Retrieved 2011/04/19.