Stannane, dibutyldiiodo-

Base Information

• Chemical Name: Stannane, dibutyldiiodo-
• CAS No.: 2865-19-2
• Molecular Formula: C8H18 I2 Sn
• Molecular Weight: 486.75
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID70182807
• Mol file: 2865-19-2.mol

Synonyms:Dibutyltin diiodide;Stannane, dibutyldiiodo-;Dibutyldiiodostannane;Tin, dibutyl-, diiodide;2865-19-2;dibutyl(diiodo)stannane;C8H18I2Sn;C8-H18-I2-Sn;DTXSID70182807;LS-146509

Chemical Property of Stannane, dibutyldiiodo-

Chemical Property:

• Vapor Pressure: 0.00103mmHg at 25°C
• Boiling Point: 311.4°Cat760mmHg
• Flash Point: 142.1°C
• PSA: 0.00000
• Density: g/cm³
• LogP: -3.13160
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 487.85200
• Heavy Atom Count: 11
• Complexity: 84.1

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): A poison by ingestion. Moderately toxic by skin contact. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
• Hazard Codes: A poison by ingestion. Moderately toxic by skin contact. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(I)I

Technology Process of Stannane, dibutyldiiodo-

There total 2 articles about Stannane, dibutyldiiodo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(C4H9)2ISnCH(CH3)CH(CH3)O2CCH3 → (Z)-2-Butene (590-18-1) + iodoacetoxydibutylstannane + dibutyl tin diiodide (2865-19-2) + dibutyltin diacetate (1067-33-0)

Guidance literature:

In neat (no solvent); heating at 50°C for a few hours; same result in CCl4 at 50°C;

DOI:10.1021/om00059a068

Reference yield: 100.0%

(C4H9)2ISnCH(CH3)CH(CH3)O2CCH3 → iodoacetoxydibutylstannane + trans-2-Butene (624-64-6) + dibutyl tin diiodide (2865-19-2) + dibutyltin diacetate (1067-33-0)

Guidance literature:

In neat (no solvent); heating at 50°C for a few hours; same result in CCl4 at 50°C;

DOI:10.1021/om00059a068

Reference yield: 88.0%

cyclohexylallene (5664-17-5) + dibutyl tin diiodide (2865-19-2) + dibutylstannane (1002-53-5) → C6H11CHC(SnI(C4H9)2)CH3 (1006895-40-4) + C6H11CH2C(CH2)SnI(C4H9)2 (1006895-47-1)

Guidance literature:

In tetrahydrofuran; to an equimol. mixture of Sn compds., added THF, then added 2 equiv. of allene, stirred at room temp. for 17 h; E:Z=58:42;

DOI:10.1039/b712998j

Downstream raw materials:

tributyltin iodide

dibutylstannane

(CH₃)2C(C₆H₅)CHC(SnI(C₄H₉)2)CH₃

C₆H₁₁CHC(SnI(C₄H₉)2)CH₃

Refernces