VINYL CINNAMATE

Base Information

• Chemical Name: VINYL CINNAMATE
• CAS No.: 3098-92-8
• Molecular Formula: C₁₁H₁₀O₂
• Molecular Weight: 174.199
• Hs Code.: 2916399090
• Mol file: 3098-92-8.mol

Synonyms:Cinnamicacid, vinyl ester (6CI,7CI,8CI); Vinyl cinnamate

Chemical Property of VINYL CINNAMATE

Chemical Property:

• Vapor Pressure: 0.00836mmHg at 25°C
• Melting Point: 125℃
• Refractive Index: 1.5830
• Boiling Point: 267°Cat760mmHg
• Flash Point: 106°C
• PSA: 26.30000
• Density: 1.075g/cm³
• LogP: 2.38650
• Storage Temp.: 2-8°C
• Solubility.: soluble in Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

Vinyl Cinnamate (stabilized with MEHQ) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/38:Irritating to eyes and skin.
• Hazard Codes: R36/38:Irritating to eyes and skin.
• Statements: 36/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of VINYL CINNAMATE

There total 3 articles about VINYL CINNAMATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

vinyl acetate (108-05-4,9003-20-7) + Cinnamic acid (621-82-9) → cinnamic acid vinyl ester (17719-70-9,3098-92-8,24968-99-8)

Guidance literature:

vinyl acetate; Cinnamic acid; With mercury(II) diacetate; In tetrahydrofuran; at 20 ℃; for 0.5h;

With boron trifluoride diethyl etherate; In tetrahydrofuran; at 40 ℃; for 4h;

DOI:10.1016/j.bmcl.2013.07.051

Reference yield: 40.0%

(vinyl)trimethoxylsilane (2768-02-7) + Cinnamic acid (621-82-9) → cinnamic acid vinyl ester (17719-70-9,3098-92-8,24968-99-8)

Guidance literature:

With copper (II)-fluoride; silver fluoride; In toluene; at 130 ℃; for 24h; Sealed tube;

DOI:10.1055/s-0029-1218759

Reference yield:

→ cinnamic acid vinyl ester (17719-70-9,3098-92-8,24968-99-8)

Guidance literature:

With Mercurous acetate; In tetrahydrofuran; for 0.05h; Inert atmosphere; Sealed tube;

With sulfuric acid; In tetrahydrofuran; at 60 - 65 ℃; for 12h; Inert atmosphere; Sealed tube;

upstream raw materials:

(vinyl)trimethoxylsilane

Cinnamic acid

vinyl acetate

Downstream raw materials:

(3R)-1-hepten-3-ol

ethyl 3-phenyl-2-propenoate

ethyl dihydrocinnamate

vinyl 3-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate

Refernces

• 1、 Mastihubova, Maria,Mastihuba, Vladimir. "Donor specificity and regioselectivity in Lipolase mediated acylations of methyl α-d-glucopyranoside by vinyl esters of phenolic acids and their analogues". supporting information. p. 5389 - 5392. Retrieved 2013/09/23.