[(Chlorostannanetriyl)tris(methylene)]tris(trimethylsilane)

Base Information

• Chemical Name: [(Chlorostannanetriyl)tris(methylene)]tris(trimethylsilane)
• CAS No.: 34570-67-7
• Molecular Formula: C12H33ClSi3Sn
• Molecular Weight: 415.814
• DSSTox Substance ID: DTXSID40503383
• Mol file: 34570-67-7.mol

Synonyms:34570-67-7;[(Chlorostannanetriyl)tris(methylene)]tris(trimethylsilane);DTXSID40503383

Chemical Property of [(Chlorostannanetriyl)tris(methylene)]tris(trimethylsilane)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 416.060061
• Heavy Atom Count: 17
• Complexity: 207

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)C[Sn](C[Si](C)(C)C)(C[Si](C)(C)C)Cl

Technology Process of [(Chlorostannanetriyl)tris(methylene)]tris(trimethylsilane)

There total 4 articles about [(Chlorostannanetriyl)tris(methylene)]tris(trimethylsilane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bis[bis(trimethylsilyl)amido][[(trimethylsilyl)methyl]stannyl]praseodymium*0.5(dimethoxyethane) → chloro-trimethyl-silane (75-77-4) + hydrogen (1333-74-0) + praseodymium(III) chloride (10361-79-2) + Chlor-tris<(trimethylsilyl)methyl>zinn (34570-67-7) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; mixt. od dry HCl (excess), Pr/Sn-complex and THF keeping dor 1 d at room temp., THF replacing by hexane in usual way; ppt. filtration of, hexane-soln. evapn. (vac.), residue crystn. twice (hexane, -70°C), GLC of volatiles;

Reference yield: 95.7%

tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane (74559-43-6) → methane (34557-54-5,27936-85-2) + hydrogen (1333-74-0) + praseodymium(III) chloride (10361-79-2) + Chlor-tris<(trimethylsilyl)methyl>zinn (34570-67-7)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; soln. of Pr compd. and dry HCl (1:6 mol) was shaken for 1 h at room temp.; formed ppt. of PrCl3 was filtered off, washed with THF and dried; org. layer was sepd. by distn in vac.;

DOI:10.1016/S0022-328X(00)85913-6

Reference yield: 93.1%

dichloro[tris[(trimethylsilyl)methyl]stannyl]praseodymium*0.5(1,2-dimethoxyethane) → hydrogen (1333-74-0) + praseodymium(III) chloride (10361-79-2) + Chlor-tris<(trimethylsilyl)methyl>zinn (34570-67-7)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; mixt. od dry HCl (excess), Pr/Sn-complex and THF keeping dor 1 d at room temp., THF replacing by hexane in usual way; ppt. filtration of, hexane-soln. evapn. (vac.), residue crystn. twice (hexane, -70°C), GLC of volatiles;

upstream raw materials:

tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane

Refernces