Phosphoric acid, diphenyl ester, potassium salt

Base Information

• Chemical Name: Phosphoric acid, diphenyl ester, potassium salt
• CAS No.: 6921-14-8
• Molecular Formula: C12H11O4P.K
• Molecular Weight: 288.281
• Mol file: 6921-14-8.mol

Synonyms:

Chemical Property of Phosphoric acid, diphenyl ester, potassium salt

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphoric acid, diphenyl ester, potassium salt

There total 2 articles about Phosphoric acid, diphenyl ester, potassium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

9-diphenylphosphono-10-methylacridane → 10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + Diphenyl potassium phosphate (6921-14-8)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran;

DOI:10.1021/jo030046l

Reference yield:

phosphoric acid methyl ester diphenyl ester (115-89-9) → Diphenyl potassium phosphate (6921-14-8) + methyl iodide (74-88-4)

Guidance literature:

With (K*PHDB 18-crown-6)I; In chlorobenzene; at 60 ℃; Further Variations:; Reagents; Solvents; Kinetics;

DOI:10.1039/b105877k

Reference yield: 95.0%

Diphenyl potassium phosphate (6921-14-8) + n-Butyldiphenylsulfoniumtetrafluoroborat → diphenyl sulfide (139-66-2) + butyl diphenyl phosphate (2752-95-6)

Guidance literature:

With potassium carbonate; In dichloromethane; for 10h; Heating;

DOI:10.1055/s-1982-29784

upstream raw materials:

phosphoric acid methyl ester diphenyl ester

Downstream raw materials:

ethyl diphenyl phosphate

diphenyl sulfide

isopropyl diphenyl phosphate

butyl diphenyl phosphate

Refernces

• 1、 Motoyoshiya, Jiro,Ikeda, Tsuneaki,Tsuboi, Shuji,Kusaura, Tatsuya,Takeuchi, Yoshino,Hayashi, Satoko,Yoshioka, Sachiko,Takaguchi, Yutaka,Aoyama, Hiromu. "Chemiluminescence in autoxidation of phosphonate carbanions. Phospha-1,2-dioxetanes as the most likely high-energy intermediates". . p. 5950 - 5955. Retrieved 2007/10/03.