Methylmercury(1+);iodide

Base Information

• Chemical Name: Methylmercury(1+);iodide
• CAS No.: 143-36-2
• Molecular Formula: CH3 Hg I
• Molecular Weight: 342.529
• Hs Code.: 2931900090
• Mol file: 143-36-2.mol

Synonyms:SCHEMBL5283556;M0258

Chemical Property of Methylmercury(1+);iodide

Chemical Property:

• Melting Point: 143-144oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.46700
• Sensitive.: Light Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 343.89859
• Heavy Atom Count: 3
• Complexity: 2

Purity/Quality:

98%min ^*data from raw suppliers

Methylmercury(II) iodide, 98+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+,N
• Hazard Codes: T+,N
• Statements: 26/27/28-33-50/53
• Safety Statements: 13-28-36-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Hg+].[I-]

Technology Process of Methylmercury(1+);iodide

There total 40 articles about Methylmercury(1+);iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl(phenyl)zirconium etherate + mercury dichloride → ZrCl4*3(C2H5)2O + methylmercury(II) iodide (143-36-2) + phenylmercury(II) chloride (100-56-1)

Guidance literature:

With potassium iodide; In tetrahydrofuran; byproducts: Hg2Cl2; heating of Zr-compd. and HgCl2 (80°C, 4 h), solvent removal (vac.), distn. with water vapour into aq. KI (pptn.); filtration, drying;

DOI:10.1016/S0020-1693(00)91037-5

Reference yield:

phosphorous (12185-10-3) + water-d2 (7789-20-0) + dibenzoyl peroxide (94-36-0) → trideutero hypophosphorous acid (57583-56-9) + deuterophosphorous acid (57583-55-8) + [D3]phosphoric acid (14335-33-2)

Guidance literature:

In water-d2; toluene; Ar, P4 (or soln. of P4 in toluene) added in small portions, heated to 60-60°C, stirred for 0.5-4 h; not isolated, detected by NMR; Kinetics;

DOI:10.1016/j.molcata.2006.11.046

Reference yield:

tert.-butylhydroperoxide (75-91-2) + phosphorous (12185-10-3) + water-d2 (7789-20-0) → trideutero hypophosphorous acid (57583-56-9) + deuterophosphorous acid (57583-55-8) + [D3]phosphoric acid (14335-33-2)

Guidance literature:

In water-d2; toluene; Ar, P4 (or soln. of P4 in toluene) added in small portions, heated to 25-60°C, stirred for 0.5-4 h; not isolated, detected by NMR; Kinetics;

DOI:10.1016/j.molcata.2006.11.046

upstream raw materials:

methyl magnesium iodide

mercury(II) diacetate

dimethylmercury

trimethylaluminum

Downstream raw materials:

methyl mercury acetate

dimethylmercury

dimethyl zinc(II)

diethylmercury

Refernces

• 1、 Fukuzumi, S.,Kochi, J. K.. "Charge-Transfer Mechanism for Electrophilic Reactions. SE2 Cleavage of Alkyl Metals with Iodine". . p. 2141 - 2152. Retrieved 1980.
• 2、 Meic. "". . p. 131,132-134,136. Retrieved 1974.
• 3、 Aziz, Hannah R.,Singleton, Daniel A.. "Concert along the Edge: Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis". supporting information. p. 5965 - 5972. Retrieved 2017/05/04.
• 4、 Vadera, Khushboo,Sharma,Agarwal,Sharma, Pradeep K.. "Oxidation of lower oxyacids of phosphorus by tetraethylammonium chlorochromate: A kinetic and mechanistic study". . p. 302 - 306. Retrieved 2011/01/10.