peroxyphenylacetic acid

Base Information

• Chemical Name: peroxyphenylacetic acid
• CAS No.: 19910-09-9
• Molecular Formula: C8H8 O3
• Molecular Weight: 152.15
• Mol file: 19910-09-9.mol

Synonyms:Peroxyaceticacid, phenyl- (6CI,8CI); Phenylperacetic acid; Phenylperoxyacetic acid

Chemical Property of peroxyphenylacetic acid

Chemical Property:

• Vapor Pressure: 0.00157mmHg at 25°C
• Boiling Point: 282.6°Cat760mmHg
• Flash Point: 117.6°C
• PSA: 46.53000
• Density: 1.234g/cm³
• LogP: 1.24530

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of peroxyphenylacetic acid

There total 5 articles about peroxyphenylacetic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

phenylacetic acid (103-82-2) → peroxyphenylacetic acid (19910-09-9)

Guidance literature:

With methanesulfonic acid; dihydrogen peroxide; In water; at 5 ℃; for 3h;

DOI:10.1039/P29860000781

Reference yield: 62.0%

phenylacetyl chloride (103-80-0) → peroxyphenylacetic acid (19910-09-9)

Guidance literature:

With dihydrogen peroxide; magnesium sulfate; sodium hydroxide; In 1,4-dioxane; water; at 0 ℃; for 0.5h;

DOI:10.1002/anie.201707086

Reference yield:

4-nitrophenyl 2-phenylacetate (1223-44-5) → peroxyphenylacetic acid (19910-09-9)

Guidance literature:

With Acylase I; dihydrogen peroxide; In aq. phosphate buffer; acetonitrile; at 37 ℃; pH=7; Reagent/catalyst; Enzymatic reaction;

DOI:10.1002/cbic.202000770

upstream raw materials:

phenylacetic acid

phenylacetyl chloride

manganese(II)

phenylacetylperoxyl radical

Downstream raw materials:

((C₄H₂N)C(C₆H₂)(CH₃)3)4OFeOC(O)CH₂C₆H₅

(5,10,15,20-tetramesitylporphyrinato)oxoiron(IV)

phenylacetic acid

benzaldehyde

Refernces

• 1、 Mayer, Robert J.,Tokuyasu, Takahiro,Mayer, Peter,Gomar, Jér?me,Sabelle, Stéphane,Mennucci, Benedetta,Mayr, Herbert,Ofial, Armin R.. "Solvation Accounts for the Counterintuitive Nucleophilicity Ordering of Peroxide Anions". supporting information. p. 13279 - 13282. Retrieved 2017/10/17.
• 2、 Pande, C. S.,Jain, Neena. "PHASE TRANSFER CATALYSED PEROXIDATION OF CARBOXYLIC ACIDS WITH POTASSIUM PERSULFATE". . p. 2123 - 2128. Retrieved 2007/10/02.