CID 16212571

Base Information

• Chemical Name: CID 16212571
• CAS No.: 1068-63-9
• Molecular Formula: C2H2CsO4
• Molecular Weight: 353.83
• Hs Code.: 2917119000
• European Community (EC) Number: 213-950-8
• Wikipedia: Caesium oxalate
• Mol file: 1068-63-9.mol

Synonyms:Dicesium oxalate;1068-63-9;SCHEMBL72981

Chemical Property of CID 16212571

Chemical Property:

• Appearance/Colour: white powder
• PSA: 80.26000
• LogP: -3.51380
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 222.90076050
• Heavy Atom Count: 7
• Complexity: 71.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cesium oxalate ≥99.9% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 21/22
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(=O)(C(=O)O)O.[Cs]

Technology Process of CID 16212571

There total 13 articles about CID 16212571 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.4%

carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + caesium carbonate (534-17-8) → cesium bicarbonate (15519-28-5) + cesium oxalate (1068-63-9) + cesium formate (3495-36-1)

Guidance literature:

In neat (no solvent); High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC;

DOI:10.1039/c39950000633

Reference yield: 4.4%

carbon monoxide (201230-82-2) + caesium carbonate (534-17-8) → cesium bicarbonate (15519-28-5) + cesium oxalate (1068-63-9) + cesium formate (3495-36-1)

Guidance literature:

In neat (no solvent); High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC;

DOI:10.1039/c39950000633

Reference yield:

cesium formate (3495-36-1) → methane (34557-54-5,27936-85-2) + carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + cesium oxalate (1068-63-9) + caesium carbonate (534-17-8)

Guidance literature:

In solid; byproducts: C, CH3OH, HCO2CH3; thermal decomposition of CsHCO2 under N2 at 200-250°C; detd. by XRD and IR;

DOI:10.1007/BF01905178

upstream raw materials:

carbon dioxide

carbon monoxide

caesium carbonate

carbon dioxide

Downstream raw materials:

caesium carbonate

Dimethyl oxalate

carbonic acid dimethyl ester

Refernces

• 1、 Kudo, Kiyoshi,Ikoma, Futoshi,Mori, Sadayuki,Komatsu, Koichi,Sugita, Nobuyuki. "Novel Synthesis of Oxalate from Carbon Dioxide and Carbon Monoxide in the Presence of Caesium Carbonate". . p. 633 - 634. Retrieved 1995.
• 2、 -. "DISUBSTITUTED OXALATE AND DISUBSTITUTED CARBONATE PRODUCTION FROM AN OXALATE SALT AND ALCOHOL". Paragraph 0069. . Retrieved 2020/02/16.
• 3、 -. "PROCESS FOR THE PREPARATION OF OXALIC ACID ESTERS FROM CESIUM OXALATE". Paragraph 0031; 0051. . Retrieved 2018/09/08.