Undecanoic acid butyl ester

Base Information

• Chemical Name: Undecanoic acid butyl ester
• CAS No.: 10580-24-2
• Molecular Formula: C15H30 O2
• Molecular Weight: 242.402
• Hs Code.: 2915900090
• Mol file: 10580-24-2.mol

Synonyms:Butylundecanoate; Butyl undecylate

Chemical Property of Undecanoic acid butyl ester

Chemical Property:

• Vapor Pressure: 0.00208mmHg at 25°C
• Boiling Point: 290.3°Cat760mmHg
• Flash Point: 130°C
• PSA: 26.30000
• Density: 0.866g/cm³
• LogP: 4.86050

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Undecanoic acid butyl ester

There total 6 articles about Undecanoic acid butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-dodecene (112-41-4,25067-08-7,62132-67-6) + 1-tetradecene (1120-36-1) + 1-Decene (872-05-9,17438-89-0,25189-70-2) + 1-undecene (821-95-4) + 1-tridecene (2437-56-1) + 1-pentadecene (13360-61-7) + carbon monoxide (201230-82-2) + butan-1-ol (71-36-3) → butyl undecanoate (10580-24-2) + butyl laurate (106-18-3) + n-butyl tridecanoate (28267-31-4) + n-butyl myristate (110-36-1) + butyl palmitate (111-06-8) + Butyl pentadecanoate (35996-97-5)

Guidance literature:

With pyridine; dicobalt octacarbonyl; at 160 ℃; for 24h; under 60006 - 75007.5 Torr; Conversion of starting material;

Reference yield:

1-Decene (872-05-9,17438-89-0,25189-70-2) + n-butyl formate (592-84-7) → butyl undecanoate (10580-24-2) + rac-1-butyl 2-methyldecanoate (91526-41-9)

Guidance literature:

With carbon monoxide; bis(diphenylphosphino)butane; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene; at 150 ℃; for 72h; under 62320 Torr; Yield given. Yields of byproduct given;

DOI:10.1039/C39890000248

Reference yield:

n-butyl formate (592-84-7) + (Z)-2-decene (20348-51-0) → butyl undecanoate (10580-24-2) + butyl 2-ethylnonanoate (108919-85-3) + rac-1-butyl 2-methyldecanoate (91526-41-9) + 2-Propyl-octanoic acid butyl ester

Guidance literature:

With carbon monoxide; bis(diphenylphosphino)butane; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene; at 150 ℃; for 72h; under 62320 Torr; Yield given. Yields of byproduct given;

DOI:10.1039/C39890000248

upstream raw materials:

1-Decene

n-butyl formate

(Z)-2-decene

trans-2-decene

Downstream raw materials:

undecyl alcohol

pentadecanol

1-dodecyl alcohol

tridecan-1-ol

Refernces

• 1、 Chepaikin, E. G.,Bezruchenko, A. P.,Benjeu, A.,Joo, A.. "MILD ALKOXYCARBONYLATION OF OLEFINS IN THE PRESENCE OF PALLADIUM COMPLEXES". . p. 669. Retrieved 1989.
• 2、 Lin, Ivan J. B.,Alper, Howard. "Regiochemical control in palladium(0) and palladium(II) catalysed alkene-formate ester carbonylation reactions". . p. 248 - 249. Retrieved 2007/10/02.