(4-Methoxyphenyl)(phenyl)iodonium trifluoromethanesulfonate

Base Information

• Chemical Name: (4-Methoxyphenyl)(phenyl)iodonium trifluoromethanesulfonate
• CAS No.: 115298-63-0
• Molecular Formula: C14H12F3IO4S
• Molecular Weight: 460.213
• Hs Code.: 2909309090
• DSSTox Substance ID: DTXSID60370539
• Mol file: 115298-63-0.mol

Synonyms:115298-63-0;(4-Methoxyphenyl)(phenyl)iodonium trifluoromethanesulfonate;(4-methoxyphenyl)-phenyliodanium;trifluoromethanesulfonate;AC1MC22W;(4-METHOXYPHENYL)PHENYLIODONIUM TRIFLATE;SCHEMBL361656;DTXSID60370539;(4-Methoxyphenyl)phenyl Iodonium Triflate;(4-Methoxyphenyl)(phenyl)iodonium triflate;(4-Methoxyphenyl)(phenyl)iodoniumtrifluoromethanesulfonate;Iodonium, (4-methoxyphenyl)phenyl-, salt withtrifluoromethanesulfonic acid (1:1) (9CI)

Chemical Property of (4-Methoxyphenyl)(phenyl)iodonium trifluoromethanesulfonate

Chemical Property:

• Melting Point: 109-111
• PSA: 74.81000
• LogP: 0.95580
• Storage Temp.: Flammables area
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 3
• Exact Mass: 459.94531
• Heavy Atom Count: 23
• Complexity: 314

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xn-F
• Hazard Codes: Xn-F
• Statements: 44-36/37/38-20/21/22-11
• Safety Statements: 36/37/39-26-16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)[I+]C2=CC=CC=C2.C(F)(F)(F)S(=O)(=O)[O-]

Technology Process of (4-Methoxyphenyl)(phenyl)iodonium trifluoromethanesulfonate

There total 16 articles about (4-Methoxyphenyl)(phenyl)iodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trifluorormethanesulfonic acid (1493-13-6) + (4-methoxyphenyl)phenyliodonium p-toluenesulfonate (27126-77-8) → phenyl(4-methoxyphenyl)iodonium triflate (115298-63-0)

Guidance literature:

at 20 ℃; for 1h;

DOI:10.1055/s-2008-1032050

Reference yield: 97.0%

trifluorormethanesulfonic acid (1493-13-6) + [bis(acetoxy)iodo]benzene (3240-34-4) + 4-methoxyphenylboronic acid (5720-07-0) → phenyl(4-methoxyphenyl)iodonium triflate (115298-63-0)

Guidance literature:

In dichloromethane; at 20 ℃;

DOI:10.1016/S0040-4039(00)00861-3

Reference yield: 87.0%

trifluorormethanesulfonic acid (1493-13-6) + para-iodoanisole (696-62-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → phenyl(4-methoxyphenyl)iodonium triflate (115298-63-0)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - 20 ℃; for 0.333333h;

DOI:10.1002/chem.201300860

upstream raw materials:

trifluorormethanesulfonic acid

[bis(acetoxy)iodo]benzene

methoxybenzene

iodosylbenzene

Downstream raw materials:

biphenyl

4-methoxylbiphenyl

1,4-benzenedicarboxylic acid dimethyl ester

methyl 4-iodobenzoate

Refernces

• 1、 Kitamura,Matsuyuki,Taniguchi. "Improved preparation of diaryliodonium triflates". . p. 147 - 148. Retrieved 1994.
• 2、 Egalahewa, Sathsara,Albayer, Mohammad,Aprile, Antonino,Dutton, Jason L.. "Diverse Reactions of Thiophenes, Selenophenes, and Tellurophenes with Strongly Oxidizing I(III) PhI(L)2 Reagents". supporting information. p. 1282 - 1288. Retrieved 2017/02/15.
• 3、 Tinnis, Fredrik,Stridfeldt, Elin,Lundberg, Helena,Adolfsson, Hans,Olofsson, Berit. "Metal-free n -arylation of secondary amides at room temperature". . p. 2688 - 2691. Retrieved 2015/06/16.