9h-Carbazole-3,6-dicarboxylic acid

Base Information

• Chemical Name: 9h-Carbazole-3,6-dicarboxylic acid
• CAS No.: 3215-41-6
• Molecular Formula: C₁₄H₉NO₄
• Molecular Weight: 255.23
• NSC Number: 39033
• DSSTox Substance ID: DTXSID60284788
• Nikkaji Number: J803.089H
• Wikidata: Q82019909
• Mol file: 3215-41-6.mol

Synonyms:9h-carbazole-3,6-dicarboxylic acid;3215-41-6;9H-Carbazole-3,6-dicarboxylicacid;9H-3,6-Carbazoledicarboxylic acid;NSC39033;SCHEMBL69604;YSZC1274;Carbazole-3,6-dicarboxylic acid;DTXSID60284788;NSC 39033;NSC-39033;CS-0169914;F82890;A937696

Chemical Property of 9h-Carbazole-3,6-dicarboxylic acid

Chemical Property:

• Vapor Pressure: 5.74E-17mmHg at 25°C
• Boiling Point: 634.4°Cat760mmHg
• Flash Point: 337.5°C
• Density: 1.584g/cm³
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 255.05315777
• Heavy Atom Count: 19
• Complexity: 361

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=C1C(=O)O)C3=C(N2)C=CC(=C3)C(=O)O

Technology Process of 9h-Carbazole-3,6-dicarboxylic acid

There total 9 articles about 9h-Carbazole-3,6-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

9H-carbazole-3,6-dicarbonitrile (57103-03-4) → 9H-carbazole-3,6-dicarboxylic acid (3215-41-6)

Guidance literature:

With copper(l) iodide; sodium hydroxide; In water; for 35h; Reflux;

DOI:10.1055/s-0033-1340557

Reference yield: 60.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + pyrographite (7440-44-0) → 9H-carbazole-3,6-dicarboxylic acid (3215-41-6)

Guidance literature:

9H-carbazole; With hydrogenchloride; aluminum (III) chloride; trichloroacetonitrile; In chlorobenzene; at 20 - 100 ℃;

With potassium hydroxide; In water; for 2h; Reflux;

pyrographite; for 2h;

Reference yield: 60.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + trichloroacetonitrile (545-06-2) → 9H-carbazole-3,6-dicarboxylic acid (3215-41-6)

Guidance literature:

9H-carbazole; trichloroacetonitrile; With hydrogenchloride; aluminum (III) chloride; Heating;

With potassium hydroxide; In water; Heating;

DOI:10.1055/s-0033-1340557

upstream raw materials:

3,6-dibenzoylcarbazole

9H-carbazole

trichloroacetonitrile

2,2'-(carbazole-3,6-dicarbonyl)-di-benzoic acid diethyl ester

Downstream raw materials:

9-(2-nitro-phenyl)-carbazole-3,6-dicarboxylic acid diethyl ester

9-(2-amino-phenyl)-carbazole-3,6-dicarboxylic acid diethyl ester

Refernces

• 1、 Weseliński, ?ukasz J.,Luebke, Ryan,Eddaoudi, Mohamed. "A convenient preparation of 9 H -carbazole-3,6-dicarbonitrile and 9 H -carbazole-3,6-dicarboxylic acid". . p. 596 - 599. Retrieved 2014.
• 2、 Li, Jian-Rong,Timmons, Daren J.,Zhou, Hong-Cai. "Interconversion between molecular polyhedra and metal-organic frameworks". supporting information; experimental part. p. 6368 - 6369. Retrieved 2009/09/26.