4-ALLYLOXYANISOLE

Base Information

• Chemical Name: 4-ALLYLOXYANISOLE
• CAS No.: 13391-35-0
• Molecular Formula: C10H12 O2
• Molecular Weight: 164.204
• Hs Code.: 2909309090
• Mol file: 13391-35-0.mol

Synonyms:Benzene,1-(allyloxy)-4-methoxy- (6CI,7CI,8CI); Benzene, 1-methoxy-4-(2-propenyloxy)-(9CI); 1-(Allyloxy)-4-methoxybenzene; 1-Methoxy-4-(2-propenyloxy)benzene;4-(Allyloxy)anisole; Allyl 4-methoxyphenyl ether; Allyl p-methoxyphenyl ether;NSC 149951; p-Anisole allyl ether; p-Anisyl allyl ether; p-Methoxyphenyl allylether

Chemical Property of 4-ALLYLOXYANISOLE

Chemical Property:

• Vapor Pressure: 0.0407mmHg at 25°C
• Boiling Point: 247.3°C at 760 mmHg
• Flash Point: 94.6°C
• PSA: 18.46000
• Density: 0.991g/cm³
• LogP: 2.26000

Purity/Quality:

99% ^*data from raw suppliers

4-Allyloxyanisole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 4-Allyloxyanisole is used in method for synthesizing 3-Trifluoroalkylquinoxalinone through visible light catalysis.

Technology Process of 4-ALLYLOXYANISOLE

There total 20 articles about 4-ALLYLOXYANISOLE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-methoxy-phenol (150-76-5) + allyl bromide (106-95-6) → allyl (4-methoxyphenyl) ether (13391-35-0)

Guidance literature:

With potassium carbonate; In butanone; for 12h; Heating;

DOI:10.1002/jccs.199800001

Reference yield: 100.0%

2-bromo-3-(4-methoxyphenoxy)propene (244056-16-4) → allyl (4-methoxyphenyl) ether (13391-35-0)

Guidance literature:

With sodium salt of dimethyl methylmalonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,4-dioxane; Heating;

DOI:10.1016/S0040-4039(03)00881-5

Reference yield: 99.0%

carbonic acid allyl ester 4-methoxy-phenyl ester → allyl (4-methoxyphenyl) ether (13391-35-0)

Guidance literature:

With triphenylphosphine; tetrabutylammonium tricarbonylnitrosylferrate; In tert-butyl methyl ether; at 80 ℃; for 12h; regioselective reaction;

DOI:10.1021/ol902291z

upstream raw materials:

4-methoxy-phenol

allyl bromide

thirane

sodium 4-methoxyphenolate

Downstream raw materials:

2-allyl-4-methoxyphenol

(1R,2S)-2-(4'-methoxyphenoxy)-1-phenyl-3-buten-1-ol

(Z)-1-methoxy-4-(prop-1-en-1-yloxy)benzene

trans-4-methoxyphenyl 1-propenyl ether

Refernces

• 1、 Jimenez-Gonzalez, Leticia,Alvarez-Corral, Miriam,Munoz-Dorado, Manuel,Rodriguez-Garcia, Ignacio. "A concise and diastereoselective total synthesis of cis and trans-pterocarpans". . p. 2689 - 2691. Retrieved 2005.
• 2、 Oehrngren, Per,Fardost, Ashkan,Russo, Francesco,Schanche, Jon-Sverre,Fagrell, Magnus,Larhed, Mats. "Evaluation of a nonresonant microwave applicator for continuous-flow chemistry applications". . p. 1053 - 1063. Retrieved 2012.
• 3、 Khan, Aman,Komejan, Sarah,Patel, Aagam,Lombardi, Christopher,Lough, Alan J.,Foucher, Daniel A.. "Reduction of C,O-chelated organotin(IV) dichlorides and dihydrides leading to protected polystannanes". . p. 180 - 191. Retrieved 2015.
• 4、 Fernandes, Rodney A.,Kumar, Praveen,Yadav, Sandhya S.. "Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant". . p. 427 - 443. Retrieved 2022/01/20.
• 5、 Alavi, Seyed Jamal,Seyedi, Seyed Mohammad,Saberi, Satar,Safdari, Hadi,Eshghi, Hossein,Sadeghian, Hamid. "Allylphenols as a new class of human 15-lipoxygenase-1 inhibitors". . p. 259 - 266. Retrieved 2020/10/12.