Palladium(II) iodide

Base Information

• Chemical Name: Palladium(II) iodide
• CAS No.: 7790-38-7
• Molecular Formula: I₂Pd
• Molecular Weight: 360.229
• Hs Code.: 2827600000
• DSSTox Substance ID: DTXSID90999090
• Wikipedia: Palladium(II)_iodide
• Mol file: 7790-38-7.mol

Synonyms:Palladium(II) iodide;7790-38-7;Diiodopalladium;I2Pd;PdI2;palladium (II) iodide;Palladium(II) iodide, 97%;Palladium(II) iodide, Premion?;DTXSID90999090;AKOS015902747;CS-W020902;SC10458;FT-0696277;A856169;Palladium(II) iodide, >=99.99% trace metals basis;PALLADIUM DIIODIDE;PALLADIUM IODIDE;PALLADIUM(II) IODIDE

Chemical Property of Palladium(II) iodide

Chemical Property:

• Appearance/Colour: Black Powder
• Melting Point: 350 °C (dec.)(lit.)
• PSA: 0.00000
• Density: 6.003 g/mL at 25 °C(lit.)
• LogP: -5.99200
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility.: Insoluble in H2O and organic solvents. Insoluble in diluted nitr
• Water Solubility.: Soluble in ammonia, methyl acetate and potassium iodide. Slightly soluble in hydriodic acid and concentrated nitric acid. Insolu
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 359.71243
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Palladium(II) iodide, 99% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [Pd](I)I
• Uses: Palladium(II) iodide is used in gravimetric analysis. It is involved in the synthesis of symmetrical and unsymmetrical ureas.

Technology Process of Palladium(II) iodide

There total 33 articles about Palladium(II) iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

iodine (7553-56-2,12190-71-5,8031-47-8) + palladium (7440-05-3) → palladium(II) iodide (7790-38-7)

Guidance literature:

In N,N-dimethyl-formamide; Pd was oxidized with I2 in DMF at 333 K; elem. anal.; Kinetics;

DOI:10.1023/B:RUGC.0000007607.86190.f9

Reference yield: 88.0%

(S,S)-[Pd2(κ2(C,N)-C6H4CH2CH(CO2Me)NH2-2)2(μ-Br)2] + iodine (7553-56-2,12190-71-5,8031-47-8) → trans-(S,S)-[PdBr2(NH2CH(CO2Me)CH2C6H4-I-2)2] + palladium(II) iodide (7790-38-7)

Guidance literature:

In dichloromethane; I2 added to a soln. of Pd complex, stirred for 4 h at room temp.; filtered, concd., pptd. (n-pentane), filtered, washed (n-pentane), air-dried; elem. anal.;

DOI:10.1021/om070127y

Reference yield: 70.0%

[Pd2(C,N-C6H4CH2CMe2NH2-2)2(μ-Cl)2] (871258-01-4) + iodine (7553-56-2,12190-71-5,8031-47-8) → trans-[PdCl2(NH2CMe2CH2C6H4I-2)2] (871258-03-6) + palladium(II) iodide (7790-38-7)

Guidance literature:

In dichloromethane; I2 added to a soln. of Pd complex, stirred for 2.5 h; filtered (MgSO4), concd., filtered, washed (CH2Cl2, Et2O), air-dried; elem. anal.;

DOI:10.1021/om0506522

upstream raw materials:

iodine

palladium

palladium(II) bromide

palladium (II) ion

Downstream raw materials:

({PS,3R,4R,P'S}-3,4-bis{(benzyl)phenylphosphanyl}-1-(tert-butoxycarbonyl)pyrrolidine-P,P')diiodopalladium

({PR,3R,4R,P'R}-3,4-bis{(benzyl)phenylphosphanyl}-1-(tert-butoxycarbonyl)pyrrolidine-P,P')diiodopalladium

({PR,3R,4R,P'S}-1-(tert-butoxycarbonyl)-3,4-bis{(benzyl)phenylphosphanyl}pyrrolidine-P,P')diiodopalladium

({PS,3R,4R,P'S}-1-(tert-butoxycarbonyl)-3,4-bis{(2-methoxybenzyl)phenylphosphanyl}pyrrolidine-P,P')diiodopalladium

Refernces

• 1、 Piskunov,Maslennikov,Spirina,Manuilov,Novikov,Maslennikov. "Oxidation of palladium with allyl bromide and iodine in dimethylformamide". . p. 1040 - 1042. Retrieved 2003.
• 2、 Latocheski, Eloah,Marques, Marcelo V.,Albuquerque, Brunno L.,Schuh, Thalia J.,Signori, Aline M.,Oliveira, Daniela C.,Pal, Taransankar,Domingos, Josiel B.. "On the Formation of Palladium (II) Iodide Nanoparticles: An In Situ SAXS/XAS Study and Catalytic Evaluation on an Aryl Alkenylation Reaction in Water Medium". . p. 684 - 688. Retrieved 2019/01/04.
• 3、 Aguilar, David,Navarro, Rafael,Soler, Tatiana,Urriolabeitia, Esteban P.. "Regioselective functionalization of iminophosphoranes through Pd-mediated C-H bond activation: C-C and C-X bond formation". . p. 10422 - 10431. Retrieved 2011/01/05.