Iron(II) acetate

Base Information

• Chemical Name: Iron(II) acetate
• CAS No.: 3094-87-9
• Molecular Formula: 3C₂H₃O₂*Fe
• Molecular Weight: 232.981
• Hs Code.: 29152990
• European Community (EC) Number: 221-441-7
• UNII: L80I7M6D3Q
• DSSTox Substance ID: DTXSID5037656
• Nikkaji Number: J54.940A
• Wikipedia: Iron(II)_acetate
• Wikidata: Q2657418
• Mol file: 3094-87-9.mol

Synonyms:Iron(II) acetate;3094-87-9;Ferrous acetate;Iron diacetate;iron(2+);diacetate;Iron di(acetate);Iron (II) acetate;Iron(2+) acetate;ACETIC ACID, IRON(2+) SALT;EINECS 221-441-7;L80I7M6D3Q;Iron(II) acetate, anhydrous;Acetic acid, iron(2+) salt (2:1);iron(ii)acetate;Acetic Acid Iron(II) Salt;Acetic acid, iron(2) salt;UNII-L80I7M6D3Q;SCHEMBL51266;Diacetic acid iron(II) salt;C2H4O2.1/2Fe;DTXSID5037656;LNOZJRCUHSPCDZ-UHFFFAOYSA-L;C2-H4-O2.1/2Fe;AKOS015837568;FT-0627300;I0765;D84280;Q2657418

Chemical Property of Iron(II) acetate

Chemical Property:

• Appearance/Colour: Off-white or light brown solid
• Melting Point: 190-200 °C (dec.)(lit.)
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 80.26000
• Density: decomposes at 190–200 [ALD94]
• LogP: -2.49010
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 173.961544
• Heavy Atom Count: 9
• Complexity: 25.5

Purity/Quality:

99.9% ^*data from raw suppliers

Iron(II) Acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Acids, Metal Salts
• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].[Fe+2]
• Description: Iron (II) acetate is an off-white or light brown solid ionic compound of iron. It is highly soluble in water and it forms a light green tetrahydrate. Iron (II) acetate is manufactured from scrap iron and acetic acid, and it is used as a mordant by the dye industry. Ebonizing wood is one such process. It can also be made by the reaction of ferrous oxide or ferrous hydroxide with concentrated acetic acid 。.
• Uses: Textile dyeing, medicine, dyeing leather, wood preservative. Iron(II) acetate is used as a mordant by the dye industry, as a catalyst in organic oxidation reactions and in carbon nanotube synthesis. It is used as a precursor in the production of other iron compounds.

Technology Process of Iron(II) acetate

There total 22 articles about Iron(II) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

acetic anhydride (108-24-7) + iron (7439-89-6) + acetic acid (64-19-7,77671-22-8) → iron(II) acetate (1834-30-6,2140-52-5,3094-87-9)

Guidance literature:

In acetic anhydride; acetic acid; byproducts: H2; Schlenk technique, under Ar; acetic acid and acetic anhydride heated to reflux, reacted with Fe (54 mmol) at boiling for 4 h; B. Heyn et al., Anorganische Syntesechemie, V.2, Springer, Heildeberg, 1986; ppt. filtered off, washed with Et2O, dried in vac.; elem. anal.;

DOI:10.1002/zaac.201000274

Reference yield: 77.0%

iron pentacarbonyl (13463-40-6,37220-42-1) → iron(II) acetate (1834-30-6,2140-52-5,3094-87-9)

Guidance literature:

With acetic acid; acetic anhydride; In N,N-dimethyl-formamide; N2-atmosphere; filtration of Fe(CO)5 into soln. of HOAc and acetic anhydride, heating to 80°C, then to 115 -120°C 60 h; crystn., filtration, washing (benzene), drying (vac., over H2SO4 and CaCl2); elem. anal.;

DOI:10.1039/DT9770001420

Reference yield: 65.0%

iron (7439-89-6) + acetic acid (64-19-7,77671-22-8) → iron(II) acetate (1834-30-6,2140-52-5,3094-87-9)

Guidance literature:

With hydrogenchloride; In water; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201803501

upstream raw materials:

iron

Sucrose

acetic acid

acetic anhydride

Downstream raw materials:

iron

iron(II) oxide

iron(III) tetraphenylporphyrin

{(p-OMeTPP)Fe}2O

Refernces

• 1、 Pai, Sandesh,Schott, Marco,Niklaus, Lukas,Posset, Uwe,Kurth, Dirk G.. "A study of the effect of pyridine linkers on the viscosity and electrochromic properties of metallo-supramolecular coordination polymers". . p. 3310 - 3321. Retrieved 2018/04/05.
• 2、 Pai, Sandesh,Moos, Michael,Schreck, Maximilian H.,Lambert, Christoph,Kurth, Dirk G.. "Green-to-Red Electrochromic Fe(II) Metallo-Supramolecular Polyelectrolytes Self-Assembled from Fluorescent 2,6-Bis(2-pyridyl)pyrimidine Bithiophene". . p. 1418 - 1432. Retrieved 2017/02/15.