Ethyl 10-undecenoate

Base Information

• Chemical Name: Ethyl 10-undecenoate
• CAS No.: 692-86-4
• Deprecated CAS: 36118-46-4,62453-48-9
• Molecular Formula: C13H24 O2
• Molecular Weight: 212.332
• Hs Code.: 2916190090
• European Community (EC) Number: 211-734-8
• UNII: 7P1S77T8BF
• DSSTox Substance ID: DTXSID4044828
• Nikkaji Number: J61.754G
• Wikidata: Q27268662
• Metabolomics Workbench ID: 46471
• ChEMBL ID: CHEMBL3182950
• Mol file: 692-86-4.mol

Synonyms:ETHYL 10-UNDECENOATE;692-86-4;Ethyl undec-10-enoate;Ethyl undecylenate;10-Undecenoic acid, ethyl ester;Ethyl undecenoate;Ethyl 10-undecylenate;Ethyl 10-hendecenoate;FEMA No. 2461;10-Undecenoic Acid Ethyl Ester;EINECS 211-734-8;BRN 1769949;Undecenoic acid, ethyl ester;UNII-7P1S77T8BF;AI3-00664;7P1S77T8BF;DTXSID4044828;Ethyl10-undecenoate;MFCD00009220;DUB UE;10-Undecenoic acid ethyl;Ethyl undecylenate, 97%;SCHEMBL53665;ethyl undec - 10 - enoate;CHEMBL3182950;DTXCID2024828;FEMA 2461;undec-10-enoic acid ethyl ester;ETHYL UNDECYLENATE [INCI];CHEBI:171792;ETHYL 10-UNDECENOATE [FCC];Tox21_301705;ETHYL 10-UNDECENOATE [FHFI];LMFA07010850;AKOS015893925;Ethyl 10-undecenoate, >=97%, FG;HY-W127559;LS-2752;NCGC00256131-01;CAS-692-86-4;CS-0185781;E0771;FT-0632818;E78909;Q27268662

Chemical Property of Ethyl 10-undecenoate

Chemical Property:

• Vapor Pressure: 0.00882mmHg at 25°C
• Melting Point: -38 °C
• Refractive Index: n20/D 1.439(lit.)
• Boiling Point: 258-259 °C761 mm Hg(lit.)
• Flash Point: >230 °c
• PSA: 26.30000
• Density: 0.879 g/mL at 25 °C(lit.)
• LogP: 3.85630
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 212.177630004
• Heavy Atom Count: 15
• Complexity: 164

Purity/Quality:

99.9% ^*data from raw suppliers

10-UndecenoicAcidEthylEster ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Esters, Other
• Canonical SMILES: CCOC(=O)CCCCCCCCC=C
• Uses: 10-Undecenoic Acid Ethyl Ester is used to make luminescent silicon quantum dots for imaging of cancer cells.

Technology Process of Ethyl 10-undecenoate

There total 12 articles about Ethyl 10-undecenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

ethanol (64-17-5) + 10-undecenoic acid (112-38-9) → ethyl 10-undecenenoate (692-86-4)

Guidance literature:

With monoammonium 12-tungstophosphate; for 12h; Heating;

DOI:10.1080/00397910500328266

Reference yield: 74.0%

ethyl ester of dodec-11-ynoic acid (94030-75-8) → ethyl 10-undecenenoate (692-86-4)

Guidance literature:

ethyl ester of dodec-11-ynoic acid; With triethyl borane; dichlorogallane; In tetrahydrofuran; hexane; toluene; at 0 ℃;

With hydrogenchloride; In tetrahydrofuran; hexane; toluene;

DOI:10.1021/jo0344790

Reference yield: 72.0%

chloroformic acid ethyl ester (541-41-3) + Dec-9-enylmagnesium bromide (130628-58-9) → ethyl 10-undecenenoate (692-86-4) + carbonic acid ethyl ester-dec-9-enyl ester (106095-73-2)

Guidance literature:

With copper(I) bromide; lithium bromide; In tetrahydrofuran; at 20 ℃;

DOI:10.1055/s-2007-973861

upstream raw materials:

ethanol

10-undecenoic acid

12-hydroxy-9-octadecenoic acid ethyl ester

ethyl 11-chloro-undecanoate

Downstream raw materials:

monoethyl sebacate

3-phenethyl-1-phenyl-tridec-12-en-3-ol

10-Undecen-1-ol

ethyl undecanoate

Refernces

• 1、 -. "Agent having neurotrophic factor-like activity". . . Retrieved 2016/01/25.
• 2、 Wang, Xi,Ye, Yuxuan,Zhang, Songnan,Feng, Jiajie,Xu, Yan,Zhang, Yan,Wang, Jianbo. "Copper-catalyzed C(sp3)-C(sp3) bond formation using a hypervalent iodine reagent: An efficient allylic trifluoromethylation". supporting information; experimental part. p. 16410 - 16413. Retrieved 2011/11/29.