ammonia borane

Base Information

• Chemical Name: ammonia borane
• CAS No.: 108203-18-5
• Molecular Formula: BH₄N
• Molecular Weight: 28.8495
• Mol file: 108203-18-5.mol

Synonyms:ammonia borane

Chemical Property of ammonia borane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ammonia borane

There total 28 articles about ammonia borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Diammoniak-diboran + sodium (7440-23-5) → ammonia borane (108203-18-5) + sodium tetrahydroborate (16940-66-2) + hydrogen (1333-74-0)

Guidance literature:

In ammonia; -78°C;

Reference yield:

NH4(1+)*H3BNH2BH3(1-)=(NH4)(H3BNH2BH3) (882752-93-4) → ammonia borane (108203-18-5) + ammonia (7664-41-7) + hydrogen (1333-74-0) + borohydride

Guidance literature:

With alcali metal; In not given;

DOI:10.1021/ja01585a010

Reference yield:

borane-ammonia complex (10043-11-5) → ammonia borane (108203-18-5) + hydrogen (1333-74-0)

Guidance literature:

[(κ³-C₆H₃-1,3-[OP^tBu₂]₂)Ir(H)_2]; In tetrahydrofuran; Kinetics;

DOI:10.1021/ic801161g

upstream raw materials:

sodium

sodium amidotrihydridoborate

diborane

aminodiborane

Downstream raw materials:

hydrogen

borazine

Refernces

• 1、 Li, Jun-Sheng,Zhang, Chang-Rui,Li, Bin,Cao, Feng,Wang, Si-Qing. "An improved synthesis of borazine with aluminum chloride as catalyst". . p. 1763 - 1766. Retrieved 2010.
• 2、 Wolf,Baumann,Baitalow,Hoffmann. "Calorimetric process monitoring of thermal decomposition of B-N-H compounds". . p. 19 - 25. Retrieved 2000.
• 3、 Baitalow,Baumann,Wolf,Jaenicke-R??ler,Leitner. "Thermal decomposition of B-N-H compounds investigated by using combined thermoanalytical methods". . p. 159 - 168. Retrieved 2002.
• 4、 Schultz, D. R.,Parry, R. W.,Koenig, F. J.. "". . p. 4 - 8. Retrieved 1958.
• 5、 Schaeffer, G. W.,Adams, M. D.,Koenig, F. J.. "". . p. 725 - 728. Retrieved 1956.
• 6、 Schlesinger, H. I.,Ritter, D. M.,Burg, A. B.. "". . p. 2297 - 2300. Retrieved 1938.
• 7、 Baker, R. Tom,Gordon, John C.,Hamilton, Charles W.,Henson, Neil J.,Lin, Po-Heng,Maguire, Steven,Murugesu, Muralee,Scott, Brian L.,Smythe, Nathan C.. "Iron complex-catalyzed ammonia-borane dehydrogenation. A potential route toward B-N-containing polymer motifs using earth-abundant metal catalysts". . p. 5598 - 5609. Retrieved 2012/05/20.