benzene, (1,1,3-trimethylbutyl)-

Base Information

• Chemical Name: benzene, (1,1,3-trimethylbutyl)-
• CAS No.: 4406-52-4
• Molecular Formula: C₁₃H₂₀
• Molecular Weight: 176.302
• Mol file: 4406-52-4.mol

Synonyms:(1,1,3-trimethylbutyl)benzene

Chemical Property of benzene, (1,1,3-trimethylbutyl)-

Chemical Property:

• Vapor Pressure: 0.123mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzene, (1,1,3-trimethylbutyl)-

There total 12 articles about benzene, (1,1,3-trimethylbutyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3-methyl-1-phenylbutan-1-one (582-62-7) + dimethyldichlorotitanium(IV) (35739-70-9) → (1,1,3-trimethylbutyl)benzene (4406-52-4)

Guidance literature:

In dichloromethane; at -30 - 0 ℃;

Reference yield:

2,4-dimethyl-4-phenyl-2-pentanol (5340-85-2) → (1,1,3-trimethylbutyl)benzene (4406-52-4)

Guidance literature:

With toluene-4-sulfonic acid; toluene; Hydrieren des Reaktionsprodukts an Kupferoxid-Chromoxid bei 125grad/157 at;

DOI:10.1021/ja01598a036

Reference yield:

2,4-dimethyl-3-pentanol (600-36-2) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → (1,1,3-trimethylbutyl)benzene (4406-52-4)

Guidance literature:

With aluminium trichloride; at 20 - 30 ℃;

upstream raw materials:

2-bromo-2-phenylpropane

isobutylmagnesium bromide

2,4-dimethyl-4-phenyl-2-pentanol

2-cyclohexyl-2,4-dimethyl-pentane

Downstream raw materials:

1-nitro-4-(1,1,3-trimethyl-butyl)-benzene

4-(1,1,3-trimethyl-butyl)-aniline

4-Hydroxy-1-(1.1.3-trimethyl-butyl)-benzol

Refernces

• 1、 Walter, Harald. "New carboxylic acid amides of the pyrrole series: Synthetic routes and biological aspects". scheme or table. p. 351 - 362. Retrieved 2009/01/31.