Thiophosphoryl chloride

Base Information Edit

Chemical Name:Thiophosphoryl chloride
CAS No.:3982-91-0
Molecular Formula:Cl3PS
Molecular Weight:169.399
Hs Code.:28273985
European Community (EC) Number:223-622-6
ICSC Number:0581
NSC Number:158334
UN Number:1837
UNII:II99F8594N
DSSTox Substance ID:DTXSID3063253
Nikkaji Number:J96.077B
Wikipedia:Thiophosphoryl chloride,Thiophosphoryl_chloride
Wikidata:Q419792
Mol file:3982-91-0.mol

Synonyms:phosphorus thiotrichloride;phosphoryl thiotrichloride;thiophosphoryl chloride

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Chemical Property of Thiophosphoryl chloride Edit

Chemical Property:

Appearance/Colour:UN 1837 8/PG 2
Vapor Pressure:15mmHg at 25°C
Melting Point:-35 °C
Refractive Index:n20/D 1.555(lit.)
Boiling Point:125 °C at 760 mmHg
PSA：41.90000
Density:1.789 g/cm³
LogP:3.57790
Sensitive.:moisture sensitive
Solubility.:benzene: soluble(lit.)
Water Solubility.:hydrolyzes in H2O, forming H3PO4, HCl, H2S; hydrolyzes rapidly in alkaline solutions; soluble benzene, CCl4, CS2, chloroform [MER06]
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:167.852391
Heavy Atom Count:5
Complexity:53
Transport DOT Label:Corrosive

Purity/Quality:

Safty Information:

Pictogram(s): T+
Hazard Codes:T+
Statements: 22-26-34-52/53
Safety Statements: 26-28-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Toxic Gases & Vapors -> Other Toxic Gases & Vapors
Canonical SMILES:P(=S)(Cl)(Cl)Cl
Inhalation Risk:A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
Effects of Short Term Exposure:The substance is corrosive to the eyes, skin and respiratory tract. The vapour is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. Exposure could cause death. The effects may be delayed. Medical observation is indicated.
Uses Thiophosphoryl chloride was used in the synthesis of O-ethyl dichlorothiophosphate.

Technology Process of Thiophosphoryl chloride

There total 96 articles about Thiophosphoryl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: