3-Bromo-N,N,N-trimethylpropan-1-aminium bromide

Base Information

• Chemical Name: 3-Bromo-N,N,N-trimethylpropan-1-aminium bromide
• CAS No.: 3779-42-8
• Molecular Formula: C6H15BrN^.Br
• Molecular Weight: 261
• Hs Code.: 2923900090
• European Community (EC) Number: 628-915-6
• NSC Number: 114234
• DSSTox Substance ID: DTXSID20958832
• ChEMBL ID: CHEMBL145957
• Mol file: 3779-42-8.mol

Synonyms:3-bromopropyltrimethylammonium bromide;BPTMA

Chemical Property of 3-Bromo-N,N,N-trimethylpropan-1-aminium bromide

Chemical Property:

• Melting Point: 210 °C (dec.)(lit.)
• PSA: 0.00000
• LogP: -1.51840
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 260.95508
• Heavy Atom Count: 9
• Complexity: 56

Purity/Quality:

98%, ^*data from raw suppliers

3-Bromo-N,N,N-trimethylpropan-1-aminiumBromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+](C)(C)CCCBr.[Br-]
• Uses: 3-Bromo-N,N,N-trimethylpropan-1-aminium Bromide is a compound used to prepare novel hydrophilic-hydrophobic block copolymer based on cardo poly(arylene ether sulfone)s with bis-quaternary ammonium moieties for anion exchange membranes.

Technology Process of 3-Bromo-N,N,N-trimethylpropan-1-aminium bromide

There total 7 articles about 3-Bromo-N,N,N-trimethylpropan-1-aminium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,3-dibromo-propane (109-64-8) + trimethylamine (75-50-3) → 3-bromo-N,N,N-trimethyl-1-propanaminium bromide (3779-42-8)

Guidance literature:

In tetrahydrofuran;

Reference yield: 97.0%

1-(3-phenoxypropyl)trimethylammonium bromide (28525-32-8) → 3-bromo-N,N,N-trimethyl-1-propanaminium bromide (3779-42-8)

Guidance literature:

With hydrogen bromide; at 120 ℃; for 3.5h;

DOI:10.1039/P29840000411

Reference yield:

→ 3-bromo-N,N,N-trimethyl-1-propanaminium bromide (3779-42-8)

Guidance literature:

With hydrogen bromide; at 160 ℃;

upstream raw materials:

1,3-dibromo-propane

trimethylamine

N,N′,N″-trimethyl-3-hydroxypropylammonium chloride

1-(3-phenoxypropyl)trimethylammonium bromide

Downstream raw materials:

C₁₆H₂₉N₅O₄⁽²⁺⁾*2Br^(1-)

1,1'-bis[3-(trimethylammonium)propyl]-4,4'-bipyridinium tetrachloride

N-(3-trimethylammoniumpropyl)octadecylammonium dibromide

N-(3-trimethylammoniumpropyl)hexadecylammonium dibromide

Refernces

• 1、 Lin, Chen Xiao,Huang, Xiao Ling,Guo, Dong,Zhang, Qiu Gen,Zhu, Ai Mei,Ye, Mei Ling,Liu, Qing Lin. "Side-chain-type anion exchange membranes bearing pendant quaternary ammonium groups: Via flexible spacers for fuel cells". . p. 13938 - 13948. Retrieved 2016/10/30.
• 2、 Bartsch, Richard A.,Zhao, Wenyi,Zhang, Zhi-Yi. "Facile synthesis of (ω-bromoalkyl)trimethylammonium bromides". . p. 2393 - 2398. Retrieved 2007/10/03.