3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane

Base Information

• Chemical Name: 3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane
• CAS No.: 928156-24-5
• Molecular Formula: C₇₂H₇₈N₄O₉
• Molecular Weight: 1143.43
• Mol file: 928156-24-5.mol

Synonyms:3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane

Chemical Property of 3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane

There total 1 articles about 3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

3,3,7,7-tetra(hydroxymethyl)-5-oxanonane (23235-61-2) + N-benzyl-N-phenylchloroacetamide (2653-14-7) → 3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane (928156-24-5)

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 6h; Heating;

DOI:10.1016/j.saa.2006.03.012

Reference yield:

3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane (928156-24-5) + terbium(III) nitrate hexahydrate → [Tb(3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane)][Tb(NO3)5](NO3)

Guidance literature:

In ethyl acetate; addn. dropwise of ethyl acetate soln. of Tb(NO3)3*6H2O to soln. of 3,3,7,7-tetra(N-benzyl-N-phenyl(acetamide)-2-oxymethyl)-5-oxanonane in ethyl acetate; stirring for 4 h; pptn., washing 3 times with ethyl acetate; drying in vac.; elem. anal.;

DOI:10.1016/j.saa.2006.03.012

Reference yield:

3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane (928156-24-5) + europium(III) nitrate hexahydrate → [Eu(3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane)][Eu(NO3)5](NO3)

Guidance literature:

In ethyl acetate; addn. dropwise of ethyl acetate soln. of Eu(NO3)3*6H2O to soln. of 3,3,7,7-tetra(N-benzyl-N-phenyl(acetamide)-2-oxymethyl)-5-oxanonane in ethyl acetate; stirring for 4 h; pptn., washing 3 times with ethyl acetate; drying in vac.; elem. anal.;

DOI:10.1016/j.saa.2006.03.012

upstream raw materials:

3,3,7,7-tetra(hydroxymethyl)-5-oxanonane

N-benzyl-N-phenylchloroacetamide

Refernces

• 1、 Lei, Ke-Wei,Liu, Wei-Sheng,Tan, Min-Yu. "Anion effects on the fluorescence spectra of europium and terbium complexes with a family of ether-amide type multipodal ligands". . p. 662 - 666. Retrieved 2007/10/03.