Methyl 4-chloroacetoacetate

Base Information Edit

Chemical Name:Methyl 4-chloroacetoacetate
CAS No.:32807-28-6
Molecular Formula:C5H7ClO3
Molecular Weight:150.562
Hs Code.:29183000
European Community (EC) Number:251-230-5
UNII:FVC6V863Y2
DSSTox Substance ID:DTXSID0067719
Nikkaji Number:J24.756A
Wikidata:Q72489125
ChEMBL ID:CHEMBL173804
Mol file:32807-28-6.mol

Synonyms:Methyl 4-chloroacetoacetate;32807-28-6;Methyl 4-chloro-3-oxobutanoate;methyl 4-chloro-3-oxo-butanoate;Butanoic acid, 4-chloro-3-oxo-, methyl ester;Methyl 4-chloro-3-oxobutyrate;4-Chloroacetoacetic Acid Methyl Ester;methyl-4-chloroacetoacetate;Methyl gamma-chloroacetoacetate;EINECS 251-230-5;MFCD00000938;ACETOACETIC ACID, 4-CHLORO-, METHYL ESTER;BRN 1759939;FVC6V863Y2;4-chloro-3-oxobutanoic acid methyl ester;3-03-00-01207 (Beilstein Handbook Reference);methyl chloroacetoacetate;Methyl 4-Chloroacetoaceate;methyl 4-chloro-acetoacetate;UNII-FVC6V863Y2;SCHEMBL56154;methyl-gamma-chloroacetoacetate;CHEMBL173804;DTXSID0067719;methyl 4-chloro-3-oxo-butyrate;Methyl .gamma.-chloroacetoacetate;Methyl .omega.-chloroacetoacetate;Methyl 4-chloro-3-oxobutanoate #;Methyl 4-chloroacetoacetate, 97%;BCP19731;STR04472;BBL027316;STL185651;AKOS000119618;4-chloro aceto acetic acid methyl ester;(R)-2-HYDROXYMETHYL-PENTANOICACID;3-Oxo-4-chlorobutanoic acid methyl ester;4-Chloro-3-oxo-butyric acid methyl ester;4-chloro-3-oxobutanoic acid, methyl ester;4-chloro-3-oxobutanoic acid. methyl ester;.gamma.-Chloroacetoacetic acid, methyl ester;CS-0044248;FT-0618156;methyl 4-chloranyl-3-oxidanylidene-butanoate;EN300-19679;S12341;A821427;W-106820;F0001-0971

Suppliers and Price of Methyl 4-chloroacetoacetate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl 4-chloroacetoacetate
1g
$ 95.00

TCI Chemical
Methyl 4-Chloroacetoacetate >96.0%(GC)
250mL
$ 230.00

TCI Chemical
Methyl 4-Chloroacetoacetate >96.0%(GC)
25mL
$ 40.00

SynQuest Laboratories
Methyl 4-chloroacetoacetate
25 g
$ 16.00

Sigma-Aldrich
Methyl 4-chloroacetoacetate 97%
5g
$ 157.00

Matrix Scientific
Methyl4-chloro-3-oxobutanoate 95%+
2.500g
$ 215.00

Matrix Scientific
Methyl4-chloro-3-oxobutanoate 95%+
100mg
$ 53.00

Matrix Scientific
Methyl4-chloro-3-oxobutanoate 95%+
500mg
$ 87.00

Apolloscientific
Methyl 4-chloroacetoacetate
100g
$ 80.00

Apolloscientific
Methyl 4-chloroacetoacetate
25g
$ 27.00

Total 107 raw suppliers

Chemical Property of Methyl 4-chloroacetoacetate Edit

Chemical Property:

Appearance/Colour:Clear colorless liquid to pale yellow liquid
Melting Point:14-16 °C
Refractive Index:n20/D 1.456(lit.)
Boiling Point:228.984 °C at 760 mmHg
PKA:9.54±0.46(Predicted)
Flash Point:102.778 °C
PSA：43.37000
Density:1.224 g/cm³
LogP:0.35740
Storage Temp.:Inert atmosphere,Room Temperature
Water Solubility.:71 g/L (20 ºC)
XLogP3:0.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:150.0083718
Heavy Atom Count:9
Complexity:121

Purity/Quality:

99% ^*data from raw suppliers

Methyl 4-chloroacetoacetate ^*data from reagent suppliers

Safty Information:

Pictogram(s): T
Hazard Codes:T
Statements: 25-34
Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC(=O)CC(=O)CCl
Uses γ-Chloroacetic acid derivative with acute toxicity used in the preparation of insecticides. Reacts with symmetric allylic diacetates or dicarbonates in the presence of a palladium catalyst to give dihyrofurans.

Technology Process of Methyl 4-chloroacetoacetate

There total 5 articles about Methyl 4-chloroacetoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%