DL-α-tocopherol 4-nitrobenzoate

Base Information

• Chemical Name: DL-α-tocopherol 4-nitrobenzoate
• CAS No.: 102672-59-3
• Molecular Formula: C₃₆H₅₃NO₅
• Molecular Weight: 579.821
• Mol file: 102672-59-3.mol

Synonyms:DL-α-tocopherol 4-nitrobenzoate

Chemical Property of DL-α-tocopherol 4-nitrobenzoate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of DL-α-tocopherol 4-nitrobenzoate

There total 1 articles about DL-α-tocopherol 4-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

4-nitro-benzoyl chloride (122-04-3) + Tocopherol (59-02-9,18920-62-2) → DL-α-tocopherol 4-nitrobenzoate (102672-59-3)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; for 16h; Reflux;

DOI:10.1002/chem.201803347

Reference yield: 78.0%

DL-α-tocopherol 4-nitrobenzoate (102672-59-3) → DL-α-tocopherol-4-amino benzoate

Guidance literature:

With 5%-palladium/activated carbon; hydrogen; In methanol; ethyl acetate; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1002/chem.201803347

Reference yield: 65.0%

methanol (67-56-1) + DL-α-tocopherol 4-nitrobenzoate (102672-59-3) → C38H59NO3

Guidance literature:

With aluminum (III) chloride; water; In acetonitrile; at 20 ℃; Irradiation;

DOI:10.1002/cssc.202002459

upstream raw materials:

4-nitro-benzoyl chloride

Tocopherol

Refernces