[(C₅H₅)2Ti(C₆H₄CH₃)(CH₃)]

Base Information

• Chemical Name: [(C₅H₅)2Ti(C₆H₄CH₃)(CH₃)]
• CAS No.: 86822-35-7
• Molecular Formula: C₁₈H₂₀Ti
• Molecular Weight: 284.237
• Mol file: 86822-35-7.mol

Synonyms:[(C₅H₅)2Ti(C₆H₄CH₃)(CH₃)]

Chemical Property of [(C₅H₅)2Ti(C₆H₄CH₃)(CH₃)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅H₅)2Ti(C₆H₄CH₃)(CH₃)]

There total 1 articles about [(C₅H₅)2Ti(C₆H₄CH₃)(CH₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(cyclopentadienyl)methyltitanium(IV) chloride (1278-83-7) + p-tolyllithium (2417-95-0) → [(C5H5)2Ti(C6H4CH3)(CH3)] (86822-35-7)

Guidance literature:

In diethyl ether; benzene; to cold (-20-0 °C) suspn. of Ti complex in Et2O added dropwise soln. of aryllithium in C6H6/Et2O under N2, stirred for 30 min; added aq. satd. soln. of NH4Cl, warmed to room temp., Et2O layer sepd.,dried over MgSO4, evapd., crystd. by cooling pentane soln. to -78 °C;

DOI:10.1021/om50004a026

Reference yield: 57.0%

[(C5H5)2Ti(C6H4CH3)(CH3)] (86822-35-7) → bis(cyclopentadienyl)methyltitanium(IV) chloride (1278-83-7) + [(C5H5)2TiCl(C6H4CH3)] (86822-29-9)

Guidance literature:

With hydrogenchloride; In diethyl ether; byproducts: C6H5CH3, CH4; to cold (-78 °C) soln. of Ti complex in Et2O added dropwise withstirring soln. of anhyd. HCl in Et2O under N2; warmed to room temp., evapd., monitored by NMR;

DOI:10.1021/om50004a026

Reference yield: 42.0%

[(C5H5)2Ti(C6H4CH3)(CH3)] (86822-35-7) + mercury dichloride → bis(cyclopentadienyl)methyltitanium(IV) chloride (1278-83-7) + [(C5H5)2TiCl(C6H4CH3)] (86822-29-9) + methylmercury(II) chloride (115-09-3) + 4-methylphenylmercuric chloride (539-43-5)

Guidance literature:

In [⁽²⁾H₆]acetone; to cold (-78 °C) soln. of Ti complex in acetone-d6 added soln. of HgCl2 in acetone-d6 under N2; warmed to room temp., monitored by NMR;

DOI:10.1021/om50004a026

upstream raw materials:

bis(cyclopentadienyl)methyltitanium(IV) chloride

p-tolyllithium

Downstream raw materials:

bis(cyclopentadienyl)methyltitanium(IV) chloride

[(C₅H₅)2TiCl(C₆H₄CH₃)]

methylmercury(II) chloride

4-methylphenylmercuric chloride

Refernces