azido-Rh₁₁₀-t-Boc

Base Information

• Chemical Name: azido-Rh₁₁₀-t-Boc
• CAS No.: 1027627-68-4
• Molecular Formula: C₂₅H₂₀N₄O₅
• Molecular Weight: 456.458
• Mol file: 1027627-68-4.mol

Synonyms:azido-Rh₁₁₀-t-Boc

Chemical Property of azido-Rh₁₁₀-t-Boc

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of azido-Rh₁₁₀-t-Boc

There total 1 articles about azido-Rh₁₁₀-t-Boc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3',6'-diamino-spiro[phthalan-1,9'-xanthen]-3-one (509-72-8) → azido-Rh110-t-Boc (1027627-68-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium hydride / N,N-dimethyl-formamide / Inert atmosphere

2.1: trifluoroacetic acid / dichloromethane; acetonitrile / Inert atmosphere

2.2: 2 h / 20 °C / Inert atmosphere

2.3: 1 h / 20 °C / Inert atmosphere

With sodium hydride; trifluoroacetic acid; In dichloromethane; N,N-dimethyl-formamide; acetonitrile; 2.1: Sandmeyer reaction / 2.2: Sandmeyer reaction / 2.3: Sandmeyer reaction;

DOI:10.1021/ja203661j

Reference yield:

azido-Rh110-t-Boc (1027627-68-4) → C25H22N4O5

Guidance literature:

With sodium hydrogen sulfide; In N,N-dimethyl-formamide; pH=7.4; Product distribution / selectivity; HEPES buffer;

Reference yield:

azido-Rh110-t-Boc (1027627-68-4) → N-tert-butoxycarbonyl-rhodamine 110

Guidance literature:

With hydrogen sulfide; at 25 ℃; for 1h; pH=7.4; HEPES buffer;

DOI:10.1021/ja203661j

upstream raw materials:

3',6'-diamino-spiro[phthalan-1,9'-xanthen]-3-one

Refernces