2-Methyl-2-adamantyl methacrylate

Base Information

• Chemical Name: 2-Methyl-2-adamantyl methacrylate
• CAS No.: 177080-67-0
• Molecular Formula: C15H22O2
• Molecular Weight: 234.338
• Hs Code.: 2916140000
• European Community (EC) Number: 805-868-1
• DSSTox Substance ID: DTXSID00431592
• Nikkaji Number: J769.179C
• Wikidata: Q72486558
• Mol file: 177080-67-0.mol

Synonyms:177080-67-0;2-METHYL-2-ADAMANTYL METHACRYLATE;2-Methyladamantan-2-yl methacrylate;2-Methacryloyloxy-2-methyladamantane;2-Methyl-2-adamantylmethacrylate;2-Methyl-acrylic acid 2-methyl-adamantan-2-yl ester;(2-methyl-2-adamantyl) 2-methylprop-2-enoate;2-METHYLADAMANTAN-2-YL 2-METHYLPROP-2-ENOATE;2-methacryloyloxy-2-methyladamantane (stabilized with mehq);2-Methyl-2-adamantyl-methacrylate;SCHEMBL44331;SCHEMBL12820198;SCHEMBL19102424;DTXSID00431592;FDYDISGSYGFRJM-UHFFFAOYSA-N;2-Methyladamantan-2-ylmethacrylate;BCP05231;CHA08067;MFCD04114354;AKOS015908660;AKOS016009200;SB34311;AS-72789;FT-0749191;M2260;Methacrylic Acid 2-Methyl-2-adamantyl Ester;T71941;A851739;2-Methacryloyloxy-2-methyladamantane, >/=97%,stabilized with MEHQ;2-Propenoic acid, 2-methyl-, 2-methyltricyclo[3.3.1.13,7]dec-2-yl ester

Chemical Property of 2-Methyl-2-adamantyl methacrylate

Chemical Property:

• Vapor Pressure: 0.001mmHg at 25°C
• Refractive Index: 1.516
• Boiling Point: 301.311 °C at 760 mmHg
• Flash Point: 122.772 °C
• PSA: 26.30000
• Density: 1.061 g/cm³
• LogP: 3.32050
• Storage Temp.: 2-8°C
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 234.161979940
• Heavy Atom Count: 17
• Complexity: 341

Purity/Quality:

99%min ^*data from raw suppliers

2-Methyl-2-adamantylMethacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OC1(C2CC3CC(C2)CC1C3)C

Technology Process of 2-Methyl-2-adamantyl methacrylate

There total 13 articles about 2-Methyl-2-adamantyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-methyladamantan-2-ol (702-98-7) + Methacryloyl chloride (920-46-7,26937-45-1) → 2-methyl-2-adamantyl methacrylate (177080-67-0)

Guidance literature:

With triethylamine; In 4-methyl-2-pentanone; at 80 ℃; for 24h;

Reference yield: 97.0%

2-Adamantanone (700-58-3) + methacryloyl anhydride (760-93-0) + methyllithium (917-54-4) → 2-methyl-2-adamantyl methacrylate (177080-67-0)

Guidance literature:

2-Adamantanone; methyllithium; In tetrahydrofuran; diethyl ether; at -25 - -20 ℃; for 1h;

methacryloyl anhydride; With triethylamine; In tetrahydrofuran; diethyl ether; at 25 ℃; for 1.5h;

Reference yield: 96.0%

2-Adamantanone (700-58-3) + methyllithium (917-54-4) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-methyl-2-adamantyl methacrylate (177080-67-0)

Guidance literature:

2-Adamantanone; methyllithium; In tetrahydrofuran; diethyl ether; at -25 - -20 ℃; for 1h;

methacrylic acid methyl ester; In tetrahydrofuran; diethyl ether; at 55 ℃; for 4.5h;

upstream raw materials:

2-Adamantanone

Methacryloyl chloride

2-methyladamantan-2-ol

poly(methacrylic acid)

Refernces

• 1、 -. "Process for Producing 2-Methyladamantan-2-Yl (Meth)Acrylate and 2-Methyladamantan-2-Yl (Meth)Acrylate". Page/Page column 4-5. . Retrieved 2008/06/13.
• 2、 -. "Processes for preparation of 2-alkyl-2adamantyl esters". . . Retrieved 2008/06/13.