n-Tetradecylboronic acid

Base Information

• Chemical Name: n-Tetradecylboronic acid
• CAS No.: 100888-40-2
• Molecular Formula: C14H31 B O2
• Molecular Weight: 242.21
• DSSTox Substance ID: DTXSID80393346
• Nikkaji Number: J2.048.671F
• Wikidata: Q82192097
• Mol file: 100888-40-2.mol

Synonyms:n-Tetradecylboronic acid;Tetradecylboronic Acid;100888-40-2;Boronic acid,B-tetradecyl-;Myristylboronic acid;TetradecylboronicAcid;Tetradecylboranic acid;n-Tetradecylboronicacid;TETRADECANEBORONIC ACID;SCHEMBL493633;1-TETRADECYLBORONIC ACID;DTXSID80393346;MCUAMUGSKSODIJ-UHFFFAOYSA-N;AKOS015909263;CS-0175909;FT-0642435

Chemical Property of n-Tetradecylboronic acid

Chemical Property:

• Vapor Pressure: 1.15E-06mmHg at 25°C
• Melting Point: 74-76°C (dec.)
• Refractive Index: 1.443
• Boiling Point: 360.9°Cat760mmHg
• PKA: 10.35±0.43(Predicted)
• Flash Point: 172.1°C
• PSA: 40.46000
• Density: 0.875g/cm³
• LogP: 4.16030
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 242.2417104
• Heavy Atom Count: 17
• Complexity: 140

Purity/Quality:

98%min ^*data from raw suppliers

N-TETRADECYL BORONIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.
• Hazard Codes: R36/37/38:Irritating to eyes, respiratory system and skin.
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(CCCCCCCCCCCCCC)(O)O

Technology Process of n-Tetradecylboronic acid

There total 5 articles about n-Tetradecylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

boric acid tributyl ester (688-74-4) + tetradecylmagnesium bromide (88303-25-7) → 1-tetradecylboronic acid (100888-40-2) + octacosane (630-02-4)

Guidance literature:

With diethyl ether;

Reference yield:

diethyl ether (60-29-7,927820-24-4) + boric acid tributyl ester (688-74-4) + tetradecylmagnesium bromide (88303-25-7) → 1-tetradecylboronic acid (100888-40-2) + octacosane (630-02-4)

Guidance literature:

Reference yield:

1-Bromotetradecane (112-71-0) → 1-tetradecylboronic acid (100888-40-2)

Guidance literature:

1-Bromotetradecane; With magnesium; iodine; In diethyl ether; for 3h; Inert atmosphere;

With Trimethyl borate; In diethyl ether; at -78 - 20 ℃; Inert atmosphere;

With hydrogenchloride; water; In diethyl ether; at 20 ℃;

upstream raw materials:

diethyl ether

boric acid tributyl ester

tetradecylmagnesium bromide

1-Bromotetradecane

Downstream raw materials:

1-Tetradecanol

Refernces

• 1、 -. "Lipase Inhibitors". Page/Page column 8-9. . Retrieved 2009/09/05.