TRANS-1,4-DICHLOROCYCLOHEXANE

Base Information

• Chemical Name: TRANS-1,4-DICHLOROCYCLOHEXANE
• CAS No.: 16890-91-8
• Molecular Formula: C6H10 Cl2
• Molecular Weight: 153.051
• Hs Code.: 2903890090
• Mol file: 16890-91-8.mol

Synonyms:trans-1,4-Dichlorocyclohexane

Chemical Property of TRANS-1,4-DICHLOROCYCLOHEXANE

Chemical Property:

• Melting Point: 103 °C
• Boiling Point: 60 °C / 3mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.77520

Purity/Quality:

98%,99%, ^*data from raw suppliers

trans-1,4-Dichlorocyclohexane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRANS-1,4-DICHLOROCYCLOHEXANE

There total 13 articles about TRANS-1,4-DICHLOROCYCLOHEXANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.9%

cyclohexyl chloride (542-18-7) → 1,1-dichlrocyclohexane (2108-92-1) + 1,3-cis-dichlorocyclohexane (24955-63-3) + trans-1,4-dichlorocyclohexane (16890-91-8) + 1,4-cis-dichlorocyclohexane (16749-11-4) + trans-1,2-dichlorocyclohexane (822-86-6) + 1,3-trans-dichlorocyclohexane (24955-62-2,24955-63-3,55887-78-0)

Guidance literature:

With chlorine; In tetrachloromethane; Product distribution; Irradiation; investigation of the photochlorination;

DOI:10.1021/ja00219a028

Reference yield:

cyclohexane (110-82-7,25012-93-5) → cyclohexyl chloride (542-18-7) + 1,3-cis-dichlorocyclohexane (24955-63-3) + trans-1,4-dichlorocyclohexane (16890-91-8) + 1,4-cis-dichlorocyclohexane (16749-11-4) + trans-1,2-dichlorocyclohexane (822-86-6) + 1,3-trans-dichlorocyclohexane (24955-62-2,24955-63-3,55887-78-0)

Guidance literature:

With chlorine; In tetrachloromethane; at 20 - 230 ℃; Product distribution; Kinetics; investigation of the free-radicals chlorination of alkanes in various solvent system;

DOI:10.1021/ja00219a028

Reference yield:

hydroquinone (123-31-9,8027-02-9) → trans-1,4-dichlorocyclohexane (16890-91-8)

Guidance literature:

Multi-step reaction with 2 steps

1: nickel catalyst; ethanol / 130 - 200 °C / 22065.2 Torr / Hydrogenation

2: concentrated aqueous HCl

With hydrogenchloride; ethanol; nickel;

upstream raw materials:

cyclohexane-1,4-diol

trans-cyclohexane-disulfonyl chloride-(1,4)

cyclohexane

cyclohexyl chloride

Refernces