oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI)

Base Information

• Chemical Name: oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI)
• CAS No.: 67584-07-0
• Molecular Formula: C₁₃H₂₁MoN₄O₈P
• Molecular Weight: 488.245
• Mol file: 67584-07-0.mol

Synonyms:oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI)

Chemical Property of oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI)

There total 7 articles about oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

oxo-(N-(C6H5)hydroxylamido-O,N)(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI) → oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI) (67584-07-0) + 1-methyl-4-nitrosobenzene (623-11-0)

Guidance literature:

With H₂O₂; In dichloromethane; water; byproducts: H2O; addn. 2 equiv 35% aq. soln. H2O2 to soln. Mo-complex/CH2Cl2, mixt. left until red-purple col. disappeared (20 min); addn. petroleum ether (pptn.), filtered;

Reference yield: 80.0%

oxo-(N-(C6H5)hydroxylamido-O,N)(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI) → oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI) (67584-07-0) + Nitrosobenzene (586-96-9)

Guidance literature:

With H₂O₂; In dichloromethane; water; byproducts: H2O; addn. 2 equiv 35% aq. soln. H2O2 to soln. Mo-complex/CH2Cl2, mixt. left until red-purple col. disappeared (20 min); addn. petroleum ether (pptn.), filtered;

Reference yield: 73.0%

oxo-(N-(C6H5)hydroxylamido-O,N)(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI) → oxoperoxo-(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI) (67584-07-0) + 1-chloro-4-nitroso-benzene (932-98-9)

Guidance literature:

With H₂O₂; In dichloromethane; water; byproducts: H2O; addn. 2 equiv 35% aq. soln. H2O2 to soln. Mo-complex/CH2Cl2, mixt. left until red-purple col. disappeared (20 min); addn. petroleum ether (pptn.), filtered;

Refernces