(1R)-2-exo-acetoxy-bornane

Base Information

• Chemical Name: (1R)-2-exo-acetoxy-bornane
• CAS No.: 28974-17-6
• Molecular Formula: C12H20 O2
• Molecular Weight: 196.29
• Hs Code.: 2915390090
• Mol file: 28974-17-6.mol

Synonyms:Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-, acetate, (1R,2R,4R)- (9CI); Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-, acetate, (1R-exo)-; Isoborneol, acetate, (1R,2R,4R)-(-)-(8CI); (-)-Isoborneol acetate; (-)-Isobornyl acetate

Chemical Property of (1R)-2-exo-acetoxy-bornane

Chemical Property:

• PSA: 26.30000
• LogP: 2.76430

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1R)-2-exo-acetoxy-bornane

There total 69 articles about (1R)-2-exo-acetoxy-bornane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

acetic anhydride (108-24-7) + 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol (507-70-0) → isobornyl acetate (76-49-3,125-12-2,5655-61-8,6626-35-3,17283-45-3,20347-65-3,28974-17-6,36386-52-4,71424-71-0,92618-89-8)

Guidance literature:

With lithium perchlorate; at 25 ℃; for 6h;

DOI:10.1055/s-2001-17483

Reference yield: 96.0%

Isopropenyl acetate (108-22-5) + 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol (507-70-0) → isobornyl acetate (76-49-3,125-12-2,5655-61-8,6626-35-3,17283-45-3,20347-65-3,28974-17-6,36386-52-4,71424-71-0,92618-89-8)

Guidance literature:

With P(MeNCH₂CH₂)3N; In tetrahydrofuran; at 50 ℃; for 16h;

DOI:10.1021/jo981819m

Reference yield: 86.0%

vinyl acetate (108-05-4,9003-20-7) + 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol (507-70-0) → isobornyl acetate (76-49-3,125-12-2,5655-61-8,6626-35-3,17283-45-3,20347-65-3,28974-17-6,36386-52-4,71424-71-0,92618-89-8)

Guidance literature:

With 2,2'-(phenylimino)bis[ethanol]; diethylzinc; In hexane; toluene; at 20 ℃; for 24h;

DOI:10.1016/j.jorganchem.2007.07.008

upstream raw materials:

benzyl thiocyanate

camphene

isoborneol

isobornyl acetate

Downstream raw materials:

dl-6-acetoxy-bornan-3-one

Camphor

5-Ketoborneol

dl-camphene

Refernces

• 1、 Bhat, Sujata V.,Gupta, Manisha O.,Yadav, Jyoti K.,Vaze, Kedar R.. "Solvent-free Acetylation Procedure". . p. 590 - 594. Retrieved 2021/10/07.
• 2、 Wijayati, Nanik,Kusumastuti, Ella,Alighiri, Dante,Rohmawati, Baiti,Lusiana, Retno Ariadi. "Heterogeneous zeolite-based catalyst for esterification of α-pinene to α-terpinyl acetate". . p. 399 - 403. Retrieved 2019/06/05.