2-phenylallyl acetate

Base Information

• Chemical Name: 2-phenylallyl acetate
• CAS No.: 7534-40-9
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.215
• Mol file: 7534-40-9.mol

Synonyms:2-phenylallyl acetate

Chemical Property of 2-phenylallyl acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-phenylallyl acetate

There total 24 articles about 2-phenylallyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + 3-phenylbut-3-enoic acid (5155-87-3) → 2-phenylallyl acetate (7534-40-9)

Guidance literature:

In acetic acid; 1,2-dichloro-ethane; at 80 ℃; for 3h; Solvent; Inert atmosphere;

DOI:10.1021/ol5022433

Reference yield: 79.0%

2-acetoxyacetophenone (2243-35-8) + Methyltriphenylphosphonium bromide (1779-49-3) → 2-phenylallyl acetate (7534-40-9)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; for 46h; Heating;

Reference yield: 78.0%

3-hydroxy-2-phenylpropene (6006-81-1) + acetic anhydride (108-24-7) → 2-phenylallyl acetate (7534-40-9)

Guidance literature:

With pyridine; dmap; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1055/s-0035-1562539

upstream raw materials:

acetic anhydride

isopropenylbenzene

propene

acetic acid

Downstream raw materials:

2-phenylglycerol

3-chloro-2-phenylprop-1-ene

2-phenyl-2-propen-1-ol 3,5-dinitrobenzoate

C₂₃H₂₀O₂

Refernces

• 1、 Jin, Can,Li, Xiaohan,Sun, Bin,Wang, Jiayang,Yang, Jin,Yu, Chuangming,Zhang, Xun,Zhuang, Xiaohui. "The Allylic Acetoxylation of 1,1-Disubstituted Alkenes Catalyzed by a Palladium(II)/Monothiadiazole Ligand System". supporting information. p. 1479 - 1483. Retrieved 2019/07/15.
• 2、 Song, Tao,Arseniyadis, Stellios,Cossy, Janine. "Highly Enantioselective, Base-Free Synthesis of α-Quaternary Succinimides through Catalytic Asymmetric Allylic Alkylation". . p. 8076 - 8080. Retrieved 2018/06/15.