4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile

Base Information

• Chemical Name: 4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile
• CAS No.: 72741-99-2
• Molecular Formula: C₄₁H₂₂N₄O₂
• Molecular Weight: 602.651
• Mol file: 72741-99-2.mol

Synonyms:4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile

Chemical Property of 4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile

There total 2 articles about 4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-Nitrophthalonitrile (31643-49-9) + 9,9-bis(4-hydroxyphenyl)fluorene (3236-71-3) → 4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile (72741-99-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃;

Reference yield:

→ 4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile (72741-99-2)

Guidance literature:

/BRN= 773336/, 1) /BRN= 877554/, N2, H2O, 2) NaOH;

Reference yield: 48.0%

4,4'-(4,4'-(9H-fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy)diphthalonitrile (72741-99-2) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → [2,10,16,24-tetrakis(9,9-bis(4-oxyphenylfluorene)phthalonitrile)phthalocyaninato]cobalt(II)

Guidance literature:

In neat (no solvent); a mixt. of C13H8(C6H4OC6H3(CN)2)2 and anhyd. CoCl2 powdered, heated in asealed tube for 5 min under N2 at 360°C; cooled to room temp., DMF added, pptd. (H2O), filtered, washed (H2O, EtOH, hot EtOH), the soluble part in THF taken, dried; elem. anal.;

DOI:10.1039/c0dt01575j

upstream raw materials:

4-Nitrophthalonitrile

9,9-bis(4-hydroxyphenyl)fluorene

Downstream raw materials:

9,9-bis[4-(3,4-dicarboxyphenoxy)phenyl]fluorene

Refernces

• 1、 Canlica, Mevlüde,Booysen, Irvin Noel,Nyokong, Tebello. "Synthesis and electrochemical behavior of novel peripherally and non-peripherally substituted ball-type cobalt phthalocyanine complexes". experimental part. p. 522 - 528. Retrieved 2011/03/21.