Nickel thiocyanate

Base Information

• Chemical Name: Nickel thiocyanate
• CAS No.: 13689-92-4
• Molecular Formula: CH N S . 1/2 Ni
• Molecular Weight: 174.857
• Hs Code.: 2930909090
• European Community (EC) Number: 237-205-1
• Wikipedia: Nickel(II)_thiocyanate
• Mol file: 13689-92-4.mol

Synonyms:nickel thiocyanate;nickel(II) thiocyanate

Chemical Property of Nickel thiocyanate

Chemical Property:

• Vapor Pressure: 4.73mmHg at 25°C
• Boiling Point: 146°Cat760mmHg
• Flash Point: 42.1°C
• PSA: 98.18000
• Density: g/cm³
• LogP: 1.32996
• Water Solubility.: g/100g solution H2O: 35.48 (25°C) [KRU93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 173.885632
• Heavy Atom Count: 7
• Complexity: 80.7

Purity/Quality:

98%Min ^*data from raw suppliers

NICKEL THIOCYANATE 98.00% ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22-45
• Safety Statements: 22-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(#N)[S-].C(#N)[S-].[Ni+2]

Technology Process of Nickel thiocyanate

There total 49 articles about Nickel thiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

nickel(II) nitrate → nickel(II) thiocyanate (13689-92-4)

Guidance literature:

With KSCN; In ethanol; KSCN reacted with metal nitrate in EtOH;

Reference yield: 86.0%

nickel(II) sulfate hexahydrate + barium thiocyanate (2092-17-3) → nickel(II) thiocyanate (13689-92-4)

Guidance literature:

nickel(II) sulfate hexahydrate; With water;

barium thiocyanate; In water; at 20 ℃;

DOI:10.1021/acs.inorgchem.0c01478

Reference yield:

manganese (II) sulfate monohydrate + nickel(II) sulfate hexahydrate + barium thiocyanate trihydrate (5908-82-7,68016-36-4) → manganese(II) thiocyanate (25327-03-1) + nickel(II) thiocyanate (13689-92-4)

Guidance literature:

In water;

DOI:10.1002/ejic.201500473

upstream raw materials:

Ni⁽²⁺⁾*NCS^(1-) = Ni(NCS)⁽¹⁺⁾

Thiocyanate

potassium thioacyanate

nickel(II) carbonate

Downstream raw materials:

{(C₅H₃N)NC(C₆H₅)CH₂C(C₆H₅)N(C₅H₃N)NC(C₆H₅)CH₂C(C₆H₅)N}Ni(NCS)2

trans-[bis(isothiocyanato)-(3,3'-oxybis[(di-meta-tolylphosphino)methyl]benzene)-nickel]

Ni(C₉H₆NC(O)NHC₆H₄NH₂)2(NCS)2

Ni(C₆H₅NHCH₂CH₂NC₂(CH₃)2NOH)2(NCS)2

Refernces

• 1、 Viltange, M.. "". . . Retrieved 1965.
• 2、 Murakawa, Shigemi,Wakamatsu, Tomio,Nakano, Motohiro,Soral, Michio,Suga, Hiroshi. "A very low-temperature calorimeter with a (3He + 4He) dilution refrigerator. The heat capacity of trans-bis(ethylenediamine)-bis(isothiocyanato)nickel(II)". . p. 1275 - 1292. Retrieved 1987.
• 3、 Andruh, M.,Urbanovici, E.,Brezeanu, M.,Segal, E.. "". . p. 257 - 266. Retrieved 1985.
• 4、 Jona,Simon,Jorik,Koman. "A thermochemical investigation of guest-host interactions in labile Werner clathrates of the [Ni(4-EtPy)4(NCS)2]·G type (G = methyl derivatives of benzene)". . p. 219 - 225. Retrieved 1997.
• 5、 Lomjansky,Moncol,Rajnák,Titi?,Bo?a. "Field effects to slow magnetic relaxation in a mononuclear Ni(II) complex". . p. 6930 - 6932. Retrieved 2017.
• 6、 Suckert, Stefan,Rams, Micha?,Rams, Marek M.,N?ther, Christian. "Reversible and Topotactic Solvent Removal in a Magnetic Ni(NCS)2 Coordination Polymer". . p. 8007 - 8017. Retrieved 2017.
• 7、 Ceglarska, Magdalena,Dinnebier, Robert E.,Gallo, Gianpiero,N?ther, Christian,Neumann, Tristan,Rams, Micha?,Wellm, Carsten. "New isomeric Ni(NCS)2 coordination compounds: Crystal structures, magnetic properties as well as: Ex situ and in situ investigations on their synthesis and transition behaviour". . p. 2350 - 2360. Retrieved 2020.
• 8、 Logan,Carle. "". . p. 5224. Retrieved 1952.
• 9、 Krebs, Christoph,Ceglarska, Magdalena,N?ther, Christian. "Synthesis, Crystal Structures and Properties of Polymorphic and Isomeric Nickel(II)thiocyanate Coordination Compounds with 3-Bromopyridine as Coligand". . p. 552 - 559. Retrieved 2021.
• 10、 Jochim, Aleksej,Ceglarska, Magdalena,Rams, Micha?,N?ther, Christian. "Synthesis, Crystal Structures, and Properties of Ni(NCS)2-4-methoxypyridine Coordination Compounds". . p. 1760 - 1770. Retrieved 2018.