Phenylazanium;bromide

Base Information

• Chemical Name: Phenylazanium;bromide
• CAS No.: 542-11-0
• Molecular Formula: C6H8BrN
• Molecular Weight: 174.04
• Hs Code.: 2921419000
• Mol file: 542-11-0.mol

Synonyms:phenylazanium;bromide;SCHEMBL8928621;NS00080250

Chemical Property of Phenylazanium;bromide

Chemical Property:

• Vapor Pressure: 0.733mmHg at 25°C
• Melting Point: 285°C(dec.)(lit.)
• Refractive Index: ">
• Boiling Point: 184.4°Cat760mmHg
• Flash Point: 70°C
• PSA: 26.02000
• Density: g/cm³
• LogP: 2.80810
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 172.98401
• Heavy Atom Count: 8
• Complexity: 46.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Aniline Hydrobromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[NH3+].[Br-]
• Uses: Organohalide based perovskites have emerged as an important class of material for solar cell applications. Our perovskites precursors are useful for synthesizing mixed cation or anion perovskites needed for the optimization of the band gap, carrier diffusion length and power conversion efficiency of perovskites based solar cells.

Technology Process of Phenylazanium;bromide

There total 33 articles about Phenylazanium;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Phenyl azide (622-37-7) → aniline hydrobromide (542-11-0)

Guidance literature:

With boron tribromide; In dichloromethane; at 0 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1080/00397911.2018.1542002

Reference yield: 73.0%

1-ethyl-2-bromo-pyridinium; bromide (79343-93-4) + aniline (62-53-3) → aniline hydrobromide (542-11-0) + 2-(phenylamino)-1-ethylpyridinium bromide

Guidance literature:

In acetonitrile; at 25 ℃;

Reference yield: 70.0%

aniline (62-53-3) → aniline hydrobromide (542-11-0)

Guidance literature:

With hydrogen bromide; acetic acid; In ethyl acetate;

DOI:10.1039/c6gc00938g

upstream raw materials:

2,4-dinitrobromobenzene

ethanol

N-Phenylhydroxylamine

carbon tetrabromide

Downstream raw materials:

N,N-dimethyl-aniline

N-methylaniline

4-methyl pent-3-en-2-ol

4-methyl-1,3-pentadiene

Refernces

• 1、 Gan, Bing,Jiang, Xiaoying,Mi, Zhisheng,Zhang, Changjung,Bai, Renren,Shuai, Qi,Xie, Yuanyuan. "Straightforward synthesis of amino-3-hydroxypyridin-4-one iron chelators via BBr3-mediated tandem reduction of azides and deprotection of methyl ether". supporting information. p. 73 - 79. Retrieved 2019/01/19.
• 2、 Consiglio, Giovanni,Frenna, Vincenzo,Arnone, Caterina,Mezzina, Elisabetta,Spinelli, Domenico. "Aromatic Nucleophilic Substitution Reactions of Some 2-L-3-Nitro-5-X-thiophenes with Piperidine and Aniline in Methanol. Substituent Constants for the Thiophene System". . p. 2187 - 2190. Retrieved 2007/10/02.