Trimethyl(4-pyridyl)tin

Base Information

• Chemical Name: Trimethyl(4-pyridyl)tin
• CAS No.: 59020-06-3
• Molecular Formula: C8H13NSn
• Molecular Weight: 241.908
• Hs Code.: 2933399090
• European Community (EC) Number: 678-257-9
• DSSTox Substance ID: DTXSID20456262
• Wikidata: Q72514394
• Mol file: 59020-06-3.mol

Synonyms:Trimethyl(4-pyridyl)tin;59020-06-3;4-(trimethylstannyl)pyridine;4-Trimethylstannylpyridine;trimethyl(pyridin-4-yl)stannane;Pyridine, 4-(trimethylstannyl)-;trimethyl(4-pyridyl)stannane;SCHEMBL624761;DTXSID20456262;YCBWXJZXFUKDPU-UHFFFAOYSA-N;AB1609;MFCD03844808;AKOS015840044;T1928

Chemical Property of Trimethyl(4-pyridyl)tin

Chemical Property:

• Vapor Pressure: 0.144mmHg at 25°C
• Refractive Index: 1.5400 to 1.5440
• Boiling Point: 223.391 °C at 760 mmHg
• PKA: 5.58±0.10(Predicted)
• Flash Point: 88.904 °C
• PSA: 12.89000
• Density: 1.42 g/cm³
• LogP: 1.62680
• Storage Temp.: Freezer
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 243.007002
• Heavy Atom Count: 10
• Complexity: 100

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethyl(4-pyridyl)tin >97.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)C1=CC=NC=C1

Technology Process of Trimethyl(4-pyridyl)tin

There total 1 articles about Trimethyl(4-pyridyl)tin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

→ trimethyltin(IV)chloride (1066-45-1) + 4-trimethylstannyl-pyridine (59020-06-3)

Guidance literature:

Reference yield: 99.0%

1,3-dibromobenzene (108-36-1) + 4-trimethylstannyl-pyridine (59020-06-3) → 1,3-bis(4-pyridyl)benzene (170165-79-4)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; lithium chloride; In toluene; at 110 ℃;

DOI:10.1016/00404-0399(50)0983J-

Reference yield: 96.0%

4,4'-dibromodiphenyl ether (2050-47-7) + 4-trimethylstannyl-pyridine (59020-06-3) → 4-{4-[4-(pyridin-4-yl)phenoxy]phenyl}pyridine

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; lithium chloride; In toluene; at 110 ℃;

DOI:10.1016/00404-0399(50)0983J-

Downstream raw materials:

(2-Cyclohexyl-2H-pyridin-1-yl)-phenyl-methanone

1,4-bis(4-pyridyl)benzene

(2α,3β)-(+/-)-1-benzyloxycarbonyl-1,2,3,6-tetrahydro-2-tridecyl-3-pyridinol

2-Ethyl-2H-pyridine-1-carboxylic acid benzyl ester

Refernces