Tetrabutylammoniummethoxide

Base Information

• Chemical Name: Tetrabutylammoniummethoxide
• CAS No.: 34851-41-7
• Molecular Formula: C17H39NO
• Molecular Weight: 273.503
• Hs Code.: 2923900090
• European Community (EC) Number: 629-053-3
• DSSTox Substance ID: DTXSID70463103
• Mol file: 34851-41-7.mol

Synonyms:34851-41-7;TETRABUTYLAMMONIUMMETHOXIDE;tetrabutylammonium methoxide;methanolate;tetrabutylazanium;tetrabutylammonium methylate;tetrabutylarnmonium methoxide;SCHEMBL106567;DTXSID70463103;HPVRLMGCBINLBH-UHFFFAOYSA-N

Chemical Property of Tetrabutylammoniummethoxide

Chemical Property:

• Flash Point: 11 ºC
• PSA: 23.06000
• LogP: 5.05030
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 273.303164868
• Heavy Atom Count: 19
• Complexity: 118

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetrabutylammonium methoxide solution 20% in methanol (NT) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,T
• Hazard Codes: F,T
• Statements: 11-23/24/25-34-39/23/24/25
• Safety Statements: 7-16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.C[O-]

Technology Process of Tetrabutylammoniummethoxide

There total 4 articles about Tetrabutylammoniummethoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + tetra(n-butyl)ammonium hydrogensulfate (32503-27-8) → tetrabutyl ammonium methoxide (34851-41-7)

Guidance literature:

With sodium hydroxide; In 1,2-dichloro-benzene;

DOI:10.1016/S0040-4039(00)84622-5

Reference yield:

C16H36N(1+)*C10H11N2O8(1-) → 2-methoxy-3,5-dinitro-benzoic acid methyl ester (38102-00-0) + tetrabutyl ammonium methoxide (34851-41-7)

Guidance literature:

With (decomposition); In methanol; at 25 ℃; Rate constant; Equilibrium constant;

Reference yield:

C16H36N(1+)*C9H9N2O7(1-) → 3,5-dinitro-4-methoxybenzaldehyde (53104-41-9) + tetrabutyl ammonium methoxide (34851-41-7)

Guidance literature:

In methanol; at 25 ℃; Equilibrium constant;

upstream raw materials:

methanol

tetra(n-butyl)ammonium hydrogensulfate

Refernces

• 1、 Moss, Robert A.,Fedorynski, Michal,Kmiecik-Lawrynowicz, Grazyna,Terpinski, Jacek. "EXCHANGE REACTIONS OF DIAZIRINES: 3-X-3-METHYLDIAZIRINES AND DERIVED CARBENES". . p. 2707 - 2710. Retrieved 2007/10/02.