Methyl cis-2-isopropyl-3-cyclohexene-1-carboxylate

Base Information

• Chemical Name: Methyl cis-2-isopropyl-3-cyclohexene-1-carboxylate
• CAS No.: 104178-36-1
• Molecular Formula: C₁₁H₁₈O₂
• Molecular Weight: 182.263
• Mol file: 104178-36-1.mol

Synonyms:

Chemical Property of Methyl cis-2-isopropyl-3-cyclohexene-1-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Methyl cis-2-isopropyl-3-cyclohexene-1-carboxylate

There total 4 articles about Methyl cis-2-isopropyl-3-cyclohexene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-5-methyl-1,3-hexendiene (32763-70-5) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → Methyl trans-2-isopropyl-3-cyclohexene-1-carboxylate (74321-11-2,74321-12-3,104178-36-1) + Methyl cis-2-isopropyl-3-cyclohexene-1-carboxylate (74321-11-2,74321-12-3,104178-36-1)

Guidance literature:

With aluminium trichloride; sodium methylate; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) C₆H₆, r.t., 18 h, 2.) MeOH, reflux, 21 h;

DOI:10.1080/00021369.1980.10863937

Reference yield:

(E)-5-methyl-1,3-hexendiene (32763-70-5) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → Methyl trans-2-isopropyl-3-cyclohexene-1-carboxylate (74321-11-2,74321-12-3,104178-36-1) + Methyl cis-2-isopropyl-3-cyclohexene-1-carboxylate (74321-11-2,74321-12-3,104178-36-1)

Guidance literature:

With aluminium trichloride; sodium methylate; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) C₆H₆, r.t., 18 h, 2.) MeOH, reflux, 21 h;

DOI:10.1080/00021369.1980.10863937

Reference yield:

2-methylhexa-2,4-diene (28823-41-8) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 2-Isopropyl-cyclohexen-(3)-carbonsaeure-(1)-methylester (104178-36-1)

Guidance literature:

at 200 ℃;

upstream raw materials:

(E)-5-methyl-1,3-hexendiene

acrylic acid methyl ester

2-methylhexa-2,4-diene

Refernces