C₄₆H₂₉N₃S

Base Information

• Chemical Name: C₄₆H₂₉N₃S
• CAS No.: 1420067-28-2
• Molecular Formula: C₄₆H₂₉N₃S
• Molecular Weight: 655.822
• Mol file: 1420067-28-2.mol

Synonyms:

Chemical Property of C₄₆H₂₉N₃S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₆H₂₉N₃S

There total 9 articles about C₄₆H₂₉N₃S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

3-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole (1346669-45-1) + C22H15ClN2 (1420067-46-4) → C46H29N3S (1420067-28-2)

Guidance literature:

3-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; for 1h;

C₂₂H₁₅ClN₂; In N,N-dimethyl-formamide; mineral oil; for 24h;

Reference yield:

3-bromobiphenyl (2113-57-7) → C46H29N3S (1420067-28-2)

Guidance literature:

Multi-step reaction with 5 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

1.2: 24 h

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / toluene; ethanol / 24 h / 120 °C

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

3.2: 12 h

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / toluene; ethanol / 24 h / 120 °C

5.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h

5.2: 24 h

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; sodium hydride; sodium carbonate; In tetrahydrofuran; ethanol; hexane; N,N-dimethyl-formamide; toluene; mineral oil;

Reference yield:

3-Biphenylboronic acid (5122-95-2) → C46H29N3S (1420067-28-2)

Guidance literature:

Multi-step reaction with 4 steps

1.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / toluene; ethanol / 24 h / 120 °C

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

2.2: 12 h

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / toluene; ethanol / 24 h / 120 °C

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h

4.2: 24 h

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; sodium hydride; sodium carbonate; In tetrahydrofuran; ethanol; hexane; N,N-dimethyl-formamide; toluene; mineral oil;

upstream raw materials:

4-dibenzothiophene boronic acid

3-bromo-9H-carbazole

3-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole

C₂₂H₁₅ClN₂

Refernces