PhSCH₂CH₂CH₂OCPh₃

Base Information

• Chemical Name: PhSCH₂CH₂CH₂OCPh₃
• CAS No.: 1190600-07-7
• Molecular Formula: C₂₈H₂₆OS
• Molecular Weight: 410.58
• Mol file: 1190600-07-7.mol

Synonyms:

Chemical Property of PhSCH₂CH₂CH₂OCPh₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PhSCH₂CH₂CH₂OCPh₃

There total 1 articles about PhSCH₂CH₂CH₂OCPh₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

3-phenylthiopropanol (24536-40-1) + trityl chloride (76-83-5) → PhSCH2CH2CH2OCPh3 (1190600-07-7)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; for 48h;

DOI:10.1016/j.jorganchem.2009.05.035

Reference yield:

N,N,N,N,-tetramethylethylenediamine (110-18-9) + PhSCH2CH2CH2OCPh3 (1190600-07-7) → C34H41LiN2OS + C34H41LiN2OS

Guidance literature:

With n-butyllithium; In hexane; pentane; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2009.05.035

Reference yield:

PhSCH2CH2CH2OCPh3 (1190600-07-7) + tributyltin chloride (1461-22-9) → PhSCH(Sn(n-Bu)3)CH2CH2OCPh3 (1190600-11-3) + Ph(Sn(n-Bu)3)S(CH2)3OCPh3

Guidance literature:

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In hexane; pentane; Schlenk technique, under Ar; at -78°C to stirred soln. of n-BuLi in hexane and tmeda in pentane, added PhSCH2CH2CH2OtBu slowly via syringe; stirred for 24 h at room temp. n-Bu3SnCl added dropwise; aq. NH4Cl4 added to suspn., aq. phase extd. with Et2O, dried over Na2SO4, filtered, evapd. solvents;not isolated, detd. by (119)Sn NMR;

DOI:10.1016/j.jorganchem.2009.05.035

upstream raw materials:

3-phenylthiopropanol

trityl chloride

Downstream raw materials:

PhSCH(Sn(n-Bu)3)CH₂CH₂OCPh₃

Refernces