trans(P)-{TcBr(PMe₂Ph)2(2,2`:6`,2``-terpyridine)}OSO₂CF₃

Base Information

• Chemical Name: trans(P)-{TcBr(PMe₂Ph)2(2,2`:6`,2``-terpyridine)}OSO₂CF₃
• CAS No.: 122822-70-2
• Molecular Formula: CF₃O₃S*C₃₁H₃₃BrN₃P₂Tc
• Molecular Weight: 837.545
• Mol file: 122822-70-2.mol

Synonyms:

Chemical Property of trans(P)-{TcBr(PMe₂Ph)2(2,2`:6`,2``-terpyridine)}OSO₂CF₃

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of trans(P)-{TcBr(PMe₂Ph)2(2,2`:6`,2``-terpyridine)}OSO₂CF₃

There total 1 articles about trans(P)-{TcBr(PMe₂Ph)2(2,2`:6`,2``-terpyridine)}OSO₂CF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

2,2':6,2''-terpyridine (1148-79-4) + mer-TcBr3(P(CH3)2Ph)3 + sodium triflate (2926-30-9) → trans(P)-{TcBr(PMe2Ph)2(2,2`:6`,2``-terpyridine)}OSO2CF3 (122822-70-2)

Guidance literature:

In ethanol; N2; refluxing for 24 h;; evapd.; dissolved in CH2Cl2; chromy. (Sephadex LH-20, CH2Cl2, CH2Cl2/CCl4); third band redissolved in acetone; NaSO3CF3 in acetone added; evapd.; washed with H2O; dried in vacuo over P2O5; elem. anal.;;

upstream raw materials:

2,2':6,2''-terpyridine

sodium triflate

Refernces